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- W2144828147 abstract "We have recently reported the photo-switching process of hierarchical structures of microphase separated (MPS) cylindrical structures embedded in a liquid crystalline (LC) phase in a film of a diblock copolymer composed of amorphous poly(butyl methacrylate) (PBMA) and a light responsive LC azobenzene (Az) blocks. In the present work, homologous poly(alkyl methacrylate) of poly(hexyl methacrylate) (PHMA) and poly(octadecyl methacrylate) (PODMA) are introduced as the cylinder forming polymer block. The Az mesogens and MPS cylinders in these polymers were aligned in the in-plane direction, and the alignments were photo-switched by changing LPL irradiation direction. The PODMA containing block copolymer exhibited a different reorientation behavior from PHMA or PBMA contained block copolymer. It was suggested that the viscosity or fluidity of cylindrical polymer affect the photoswitching alignment behavior." @default.
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- W2144828147 date "2015-08-13" @default.
- W2144828147 modified "2023-10-04" @default.
- W2144828147 title "Photo-switching Behavior of Microphase Separated Structure in Liquid Crystalline Azobenzene Block Copolymers Possessing Different Poly(alkyl methacrylate) Blocks" @default.
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- W2144828147 doi "https://doi.org/10.1080/15421406.2015.1075356" @default.
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