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- W2144865791 abstract "This is the third paper of a series in which the behavior of nucleophilic solvation is investigated by a measurement of the position and the area of the O–D vibrational band of methanol-d. In a binary solution which consisted of two components remarkably different in electron-donating power, the relation between the mol fraction (n1) of the S1 component and the area fraction (n1) of S1 was not a straight line, but a concave or convex curve. This fact suggests that a component co-ordinates selectively to a deuterium atom in a methanol-d molecule. The following definition of the selectivity of nucleophilic solvation to methanol-d as a cation model of the S2 component to the S1 component is proposed: (Remark: Graphics omitted.) The selectivity of the S2 solvent to the S1 solvent was considered in detail in connection with the equilibrium constant of the nucleophilic solvation to methanol-d of the solvent; the selectivity was also found to be defined as the ratio of the equilibrium constants of the solvents used. Since there was a correlation between the equilibrium constants and the electron-donating powers, it was concluded that the selectivity of an S2 solvent to a standard solvent, S1 could be quantitatively estimated by measuring only the position of the O–D vibrational band of methanol-d in each solvent." @default.
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- W2144865791 date "1968-04-01" @default.
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- W2144865791 title "A Definition of Selectivity of Nucleophilic Solvation in a Binary Solution" @default.
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- W2144865791 doi "https://doi.org/10.1246/bcsj.41.779" @default.
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