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• W2144920393 endingPage "2774" @default.
• W2144920393 startingPage "2769" @default.
• W2144920393 abstract "Abstract The nucleophilicity of N ‐unsubstituted imines, which were generated from alkyl azides by a ruthenium‐catalyzed reaction, was investigated in the reaction with acid anhydrides. The initial products were N ‐acylimines, which isomerized to the corresponding enamides. Heating or triethylamine facilitated the isomerization of N ‐acylimines that are stable at room temperature. A wide range of acyclic and cyclic enamides containing various functional groups was successfully synthesized under mild conditions. In addition to acetic anhydride, various acid anhydrides were applicable. From the reaction with cyclic anhydrides, enamides containing carboxylic acid group were obtained. magnified image" @default.
• W2144920393 created "2016-06-24" @default.
• W2144920393 creator A5024297092 @default.
• W2144920393 creator A5044820789 @default.
• W2144920393 creator A5054668018 @default.
• W2144920393 creator A5085452096 @default.
• W2144920393 creator A5019957200 @default.
• W2144920393 date "2014-09-03" @default.
• W2144920393 modified "2023-09-27" @default.
• W2144920393 title "Exploiting the Nucleophilicity of NH Imines: Synthesis of Enamides from Alkyl Azides and Acid Anhydrides" @default.
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