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- W2145082277 endingPage "1650" @default.
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- W2145082277 abstract "Abstract Silicon and its compounds have made possible the design of new materials, which, from computers to space travel, have helped to shape the technology of our 20th century. Conversely, the demands of new technology have stimulated the fast development of silicon chemistry as part of the “renaissance” of inorganic chemistry. This article uses selected examples of predominantly organosilicon compounds to discuss in simplified terms the measurement and assignment of suitable spectroscopic “molecular fingerprints” as well as the resulting benefit for the preparative chemist. The comparison of “equivalent” states of “chemically related” molecules is emphasized, based on perturbation arguments and supporting quantum‐chemical models. Special attention is given to the relation between structure and energy, which allows us to understand and to predict the connectivity between and the spatial arrangement of silicon “building blocks”, the energy‐dependent electron distribution over the effective nuclear potentials of a molecular framework, and, especially, the partly considerable effects of “silicon substituents” on molecular properties. Future‐directed extensions and applications include polysilane band structures, Rydberg states of chromophores containing silicon centers, redox reactions and ion‐pair formation of silicon‐substituted π systems, and molecular dynamic phenomena in solution or on thermal fragmentation in the gas phase. The main objective is a set of clear and practical rules for interpreting measurements and planning experiments." @default.
- W2145082277 created "2016-06-24" @default.
- W2145082277 creator A5088845955 @default.
- W2145082277 date "1989-12-01" @default.
- W2145082277 modified "2023-10-09" @default.
- W2145082277 title "Fundamentals of Silicon Chemistry: Molecular States of Silicon‐Containing Compounds" @default.
- W2145082277 cites W1490236393 @default.
- W2145082277 cites W1519209637 @default.
- W2145082277 cites W1530419692 @default.
- W2145082277 cites W1548848570 @default.
- W2145082277 cites W1580434741 @default.
- W2145082277 cites W1580863239 @default.
- W2145082277 cites W1965912217 @default.
- W2145082277 cites W1968023974 @default.
- W2145082277 cites W1972141981 @default.
- W2145082277 cites W1976106600 @default.
- W2145082277 cites W1976204200 @default.
- W2145082277 cites W1977909118 @default.
- W2145082277 cites W1980573222 @default.
- W2145082277 cites W1983547841 @default.
- W2145082277 cites W1984389952 @default.
- W2145082277 cites W1985589413 @default.
- W2145082277 cites W1986085367 @default.
- W2145082277 cites W1988487527 @default.
- W2145082277 cites W1991248861 @default.
- W2145082277 cites W1991539205 @default.
- W2145082277 cites W1994858392 @default.
- W2145082277 cites W1997074782 @default.
- W2145082277 cites W1998196127 @default.
- W2145082277 cites W1998975905 @default.
- W2145082277 cites W1999261851 @default.
- W2145082277 cites W1999279339 @default.
- W2145082277 cites W2000918285 @default.
- W2145082277 cites W2001432909 @default.
- W2145082277 cites W2003232804 @default.
- W2145082277 cites W2003589372 @default.
- W2145082277 cites W2003664326 @default.
- W2145082277 cites W2004960985 @default.
- W2145082277 cites W2007510737 @default.
- W2145082277 cites W2009773583 @default.
- W2145082277 cites W2013265023 @default.
- W2145082277 cites W2015307023 @default.
- W2145082277 cites W2015353361 @default.
- W2145082277 cites W2019606667 @default.
- W2145082277 cites W2020686168 @default.
- W2145082277 cites W2021547686 @default.
- W2145082277 cites W2023766090 @default.
- W2145082277 cites W2029432116 @default.
- W2145082277 cites W2031813737 @default.
- W2145082277 cites W2031980127 @default.
- W2145082277 cites W2032661708 @default.
- W2145082277 cites W2035184211 @default.
- W2145082277 cites W2037790160 @default.
- W2145082277 cites W2042064947 @default.
- W2145082277 cites W2043432431 @default.
- W2145082277 cites W2047900064 @default.
- W2145082277 cites W2049392176 @default.
- W2145082277 cites W2052894954 @default.
- W2145082277 cites W2054533109 @default.
- W2145082277 cites W2054575062 @default.
- W2145082277 cites W2055018982 @default.
- W2145082277 cites W2055317000 @default.
- W2145082277 cites W2055410771 @default.
- W2145082277 cites W2058452445 @default.
- W2145082277 cites W2060013441 @default.
- W2145082277 cites W2060329958 @default.
- W2145082277 cites W2060501150 @default.
- W2145082277 cites W2060765947 @default.
- W2145082277 cites W2061850793 @default.
- W2145082277 cites W2063796966 @default.
- W2145082277 cites W2066098140 @default.
- W2145082277 cites W2068898553 @default.
- W2145082277 cites W2073222870 @default.
- W2145082277 cites W2078231424 @default.
- W2145082277 cites W2081524721 @default.
- W2145082277 cites W2082436100 @default.
- W2145082277 cites W2084758911 @default.
- W2145082277 cites W2085084067 @default.
- W2145082277 cites W2086885680 @default.
- W2145082277 cites W2089928291 @default.
- W2145082277 cites W2090148466 @default.
- W2145082277 cites W2091641850 @default.
- W2145082277 cites W2093246470 @default.
- W2145082277 cites W2097381586 @default.
- W2145082277 cites W2099133588 @default.
- W2145082277 cites W2100141615 @default.
- W2145082277 cites W2100237578 @default.
- W2145082277 cites W2105312784 @default.
- W2145082277 cites W2109632790 @default.
- W2145082277 cites W2110090705 @default.
- W2145082277 cites W2111036368 @default.
- W2145082277 cites W2111187587 @default.
- W2145082277 cites W2113372461 @default.
- W2145082277 cites W2114788420 @default.
- W2145082277 cites W2126289864 @default.
- W2145082277 cites W2129014400 @default.
- W2145082277 cites W2129361941 @default.
- W2145082277 cites W2130964590 @default.