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- W2145121557 abstract "The influence of the medium heterogeneity upon the bimolecular rate constants for the physical quenching, kq, and chemical quenching, kr, of singlet molecular oxygen O2(1Δg) by seven natural and three synthetic carotenoids (CAR) with different substituent patterns was studied in a reverse micelle system of sodium bis(2-ethylhexyl)sulfosuccinate, hexane and water. Because O2(1Δg) was generated inside the water pools of the reverse micelles by photosensitization of the water-soluble dye rose bengal and the CAR are mainly located in the external hexane pseudophase, the quenching process was interpreted using a pseudophase model for the partition of O2(1Δg) between the water pools and the organic pseudophases. The kq values were mainly dependent on the extent of the double-bond conjugation of the CAR, as demonstrated by a good empirical relationship between log(kq) and the energy E(S) of the longest wavelength transition π→π* of the CAR. In contrast, the kr values were almost independent of the extent of the double-bond–conjugated system and about four orders of magnitude lower than kq. However, in all cases, CAR photobleaching was observed with the formation of various oxidation products, depending on the photosensitization time. Chromatographic and spectroscopic product analysis for the reaction products of β-carotene with O2(1Δg) indicated the formation of the β-carotene-5,8-endoperoxide as the primary oxidation product." @default.
- W2145121557 created "2016-06-24" @default.
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- W2145121557 date "2002-01-01" @default.
- W2145121557 modified "2023-10-18" @default.
- W2145121557 title "Singlet Molecular Oxygen Quenching Ability of Carotenoids in a Reverse-micelle Membrane Mimetic System¶" @default.
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- W2145121557 doi "https://doi.org/10.1562/0031-8655(2002)075<0353:smoqao>2.0.co;2" @default.
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