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- W2145131705 abstract "Abstract s ‐Butoxy radicals have been generated by reacting fluorine with s ‐butanol: Over the temperature range 398.6 to 493.3 K the s ‐butoxy radical decomposes by two different pathways to yield acetaldehyde and propionaldehyde, acetaldehyde being the major product: equation image The ratio k 1 / k 2 was found to be temperature dependent. An Arrhenius plot of the data (398.6 to 493.3 K) yields the relative Arrhenius parameters, E 1 ‐ E 2 = −11.2 ± 0.8 kJ mol −1 and ( A 1 / A 2 ) = 0.59 ± 0.14. The ratio of rate constants k 1 / k 2 was shown to be independent of total pressure (80–600 torr) and of the pressure of s ‐butanol (2–13 torr). The kinetic results for these s ‐butoxy decomposition reactions are discussed in relation to the literature data and in terms of the thermochemistry of the reactions." @default.
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- W2145131705 date "1985-05-01" @default.
- W2145131705 modified "2023-09-27" @default.
- W2145131705 title "Relative rate constants of the gas-phase decomposition reactions of thes-butoxy radical" @default.
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- W2145131705 doi "https://doi.org/10.1002/kin.550170205" @default.
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