FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2145188758> ?p ?o ?g. }

• W2145188758 endingPage "246" @default.
• W2145188758 startingPage "236" @default.
• W2145188758 abstract "Absolute rate coefficients for the title reaction, HO + HOCH2C(O)CH3 → products (R1) were measured over the temperature range 233–363 K using the technique of pulsed laser photolytic generation of the HO radical coupled to detection by pulsed laser induced fluorescence. The rate coefficient displays a slight negative temperature dependence, which is described by: k1(233–363 K) = (2.15 ± 0.30) × 10−12 exp{(305 ± 10)/T} cm3 molecule−1 s−1, with a value of (5.95 ± 0.50) × 10−12 cm3 molecule−1 s−1 at room temperature. The effects of the hydroxy-substituent and hydrogen bonding on the rate coefficient are discussed based on theoretical calculations. The present results, which extend the database on the title reaction to a range of temperatures, indicate that R1 is the dominant loss process for hydroxyacetone throughout the troposphere, resulting in formation of methylglyoxal at all atmospheric temperatures. As part of this work, the rate coefficient for reaction of O(3P) with HOCH2C(O)CH3 (R4) was measured at 358 K: k4(358 K) = (6.4 ± 1.0) × 10−14 cm3 molecule−1 s−1 and the absorption cross section of HOCH2C(O)CH3 at 184.9 nm was determined to be (5.4 ± 0.1) × 10−18 cm2 molecule−1." @default.
• W2145188758 created "2016-06-24" @default.
• W2145188758 creator A5029999911 @default.
• W2145188758 creator A5035062040 @default.
• W2145188758 creator A5045737008 @default.
• W2145188758 creator A5065470973 @default.
• W2145188758 creator A5070864751 @default.
• W2145188758 creator A5081117962 @default.
• W2145188758 date "2006-01-01" @default.
• W2145188758 modified "2023-10-17" @default.
• W2145188758 title "Reaction of HO with hydroxyacetone (HOCH₂C(O)CH₃): rate coefficients (233–363 K) and mechanism" @default.
• W2145188758 cites W1506806294 @default.
• W2145188758 cites W1913747830 @default.
• W2145188758 cites W1983972695 @default.
• W2145188758 cites W1985026611 @default.
• W2145188758 cites W2003043031 @default.
• W2145188758 cites W2003590677 @default.
• W2145188758 cites W2009277390 @default.
• W2145188758 cites W2012224797 @default.
• W2145188758 cites W2012293080 @default.
• W2145188758 cites W2012950823 @default.
• W2145188758 cites W2014799094 @default.
• W2145188758 cites W2048128935 @default.
• W2145188758 cites W2067209936 @default.
• W2145188758 cites W2082315410 @default.
• W2145188758 cites W2083699664 @default.
• W2145188758 cites W2097249912 @default.
• W2145188758 cites W2143995683 @default.
• W2145188758 cites W2161776543 @default.
• W2145188758 cites W2316884082 @default.
• W2145188758 cites W2914650791 @default.
• W2145188758 doi "https://doi.org/10.1039/b513056e" @default.
• W2145188758 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16482266" @default.
• W2145188758 hasPublicationYear "2006" @default.
• W2145188758 type Work @default.
• W2145188758 sameAs 2145188758 @default.
• W2145188758 citedByCount "41" @default.
• W2145188758 countsByYear W21451887582012 @default.
• W2145188758 countsByYear W21451887582013 @default.
• W2145188758 countsByYear W21451887582014 @default.
• W2145188758 countsByYear W21451887582015 @default.
• W2145188758 countsByYear W21451887582016 @default.
• W2145188758 countsByYear W21451887582017 @default.
• W2145188758 countsByYear W21451887582018 @default.
• W2145188758 countsByYear W21451887582019 @default.
• W2145188758 countsByYear W21451887582020 @default.
• W2145188758 crossrefType "journal-article" @default.
• W2145188758 hasAuthorship W2145188758A5029999911 @default.
• W2145188758 hasAuthorship W2145188758A5035062040 @default.
• W2145188758 hasAuthorship W2145188758A5045737008 @default.
• W2145188758 hasAuthorship W2145188758A5065470973 @default.
• W2145188758 hasAuthorship W2145188758A5070864751 @default.
• W2145188758 hasAuthorship W2145188758A5081117962 @default.
• W2145188758 hasConcept C113196181 @default.
• W2145188758 hasConcept C121332964 @default.
• W2145188758 hasConcept C125287762 @default.
• W2145188758 hasConcept C147789679 @default.
• W2145188758 hasConcept C148898269 @default.
• W2145188758 hasConcept C155647269 @default.
• W2145188758 hasConcept C159985019 @default.
• W2145188758 hasConcept C161790260 @default.
• W2145188758 hasConcept C175113610 @default.
• W2145188758 hasConcept C178790620 @default.
• W2145188758 hasConcept C185592680 @default.
• W2145188758 hasConcept C192562407 @default.
• W2145188758 hasConcept C2778689049 @default.
• W2145188758 hasConcept C32909587 @default.
• W2145188758 hasConcept C39353612 @default.
• W2145188758 hasConcept C512968161 @default.
• W2145188758 hasConcept C62520636 @default.
• W2145188758 hasConcept C75473681 @default.
• W2145188758 hasConcept C93391505 @default.
• W2145188758 hasConcept C97355855 @default.
• W2145188758 hasConceptScore W2145188758C113196181 @default.
• W2145188758 hasConceptScore W2145188758C121332964 @default.
• W2145188758 hasConceptScore W2145188758C125287762 @default.
• W2145188758 hasConceptScore W2145188758C147789679 @default.
• W2145188758 hasConceptScore W2145188758C148898269 @default.
• W2145188758 hasConceptScore W2145188758C155647269 @default.
• W2145188758 hasConceptScore W2145188758C159985019 @default.
• W2145188758 hasConceptScore W2145188758C161790260 @default.
• W2145188758 hasConceptScore W2145188758C175113610 @default.
• W2145188758 hasConceptScore W2145188758C178790620 @default.
• W2145188758 hasConceptScore W2145188758C185592680 @default.
• W2145188758 hasConceptScore W2145188758C192562407 @default.
• W2145188758 hasConceptScore W2145188758C2778689049 @default.
• W2145188758 hasConceptScore W2145188758C32909587 @default.
• W2145188758 hasConceptScore W2145188758C39353612 @default.
• W2145188758 hasConceptScore W2145188758C512968161 @default.
• W2145188758 hasConceptScore W2145188758C62520636 @default.
• W2145188758 hasConceptScore W2145188758C75473681 @default.
• W2145188758 hasConceptScore W2145188758C93391505 @default.
• W2145188758 hasConceptScore W2145188758C97355855 @default.
• W2145188758 hasIssue "2" @default.
• W2145188758 hasLocation W21451887581 @default.
• W2145188758 hasLocation W21451887582 @default.
• W2145188758 hasOpenAccess W2145188758 @default.
• W2145188758 hasPrimaryLocation W21451887581 @default.

• next