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- W2145254626 abstract "The dynamics of the intermolecular motion of the phenol+–Kr cation generated by photoionization of the neutral π-structure is probed by picosecond time-resolved infrared spectroscopy. The spectrum at zero delay displays only the free OH stretch band of the π-structure. The appearance of the hydrogen-bonded OH stretch band of the H-structure after a few ps is due to ionization-induced π → H site switching. Spectra at long delay (>20 ns) show that the Kr atom delocalizes from one π-site of the aromatic ring to the opposite π-site via the OH-site, like a pendular motion in the classical picture." @default.
- W2145254626 created "2016-06-24" @default.
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- W2145254626 date "2011-01-01" @default.
- W2145254626 modified "2023-10-16" @default.
- W2145254626 title "Photoionization-induced large-amplitude pendular motion in phenol<sup>+</sup>–Kr" @default.
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- W2145254626 doi "https://doi.org/10.1039/c0cp01961e" @default.
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