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- W2145280649 abstract "A facile synthesis of a bicyclic 8-menthylsulfinate is described. The reaction of this sultine with organometallic compounds leads to γ-hydroxysulfoxides, while the reaction with lithium amide affords 8-menthylsulfinamide. The chiral efficiency of the 8-menthylsulfinyl auxiliary was tested in the reaction of sulfinimines with Grignard reagents. A highly stereoselective addition of ethylmagnesium bromide to 8-menthylsulfinimine was observed (98% de)." @default.
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- W2145280649 date "2003-09-01" @default.
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- W2145280649 title "New, recoverable and highly effective sulfinyl chiral auxiliary" @default.
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- W2145280649 doi "https://doi.org/10.1016/s0957-4166(03)00624-4" @default.
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