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• W2145367369 abstract "The photochemistry of the cis and trans isomers of a series of dimethylbicyclo[n 2.0]alk-(n + 2)-enes (n = 2–5) (bicyclic cyclobutene derivatives in which the C=C bond is shared by the two rings) in pentane solution is described. Irradiation of these compounds using monochromatic 193- or214-nm light sources results in ring opening to yield the corresponding 1,2-bis(1-ethylidene)cycloalkanes (C 4 –C 7 ) in high chemical and quantum yields. In all cases, the reaction proceeds with a high (70–90%) degree of disrotatory stereoselectivity. Quantum yields for direct cis,trans photoisomerization of the isomeric E,E-and E,Z-1,2-bis(1-ethylidene)cycloalkanes have also been determined. The product distributions from irradiation of the cyclobutenes are wavelength dependent, but for 214-nm excitation the isomeric diene distributions obtained from cyclobutene ring opening agree fairly closely with those calculated from the quantum yields for cis,trans photoisomerization of the isomeric dienes on the assumption that the process involves purely disrotatory ring opening to yield a single diene isomer in the lowest excited singlet state. The results are consistent with an orbital-symmetry-controlled, adiabatic mechanism for ring opening. Key words: photochemistry, cyclobutene, electrocyclic, adiabatic, conical intersection, orbital symmetry." @default.
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• W2145367369 date "1996-06-01" @default.
• W2145367369 modified "2023-10-12" @default.
• W2145367369 title "Cyclobutene photochemistry. Adiabatic photochemical ring opening of alkylcyclobutenes" @default.
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• W2145367369 doi "https://doi.org/10.1139/v96-105" @default.
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