FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2145408077> ?p ?o ?g. }

• W2145408077 endingPage "6253" @default.
• W2145408077 startingPage "6253" @default.
• W2145408077 abstract "As indicated by Gibbs and made explicit by Guggenheim, the electrical potential difference between two regions of different chemical composition cannot be measured. The Gibbs-Guggenheim Principle restricts the use of classical electrostatics in electrochemical theories as thermodynamically unsound with some few approximate exceptions, notably for dilute electrolyte solutions and concomitant low potentials where the linear limit for the exponential of the relevant Boltzmann distribution applies. The Principle invalidates the widespread use of forms of the Poisson-Boltzmann equation which do not include the non-electrostatic components of the chemical potentials of the ions. From a thermodynamic analysis of the parallel plate electrical condenser, employing only measurable electrical quantities and taking into account the chemical potentials of the components of the dielectric and their adsorption at the surfaces of the condenser plates, an experimental procedure to provide exceptions to the Principle has been proposed. This procedure is now reconsidered and rejected. No other related experimental procedures circumvent the Principle. Widely-used theoretical descriptions of electrolyte solutions, charged surfaces and colloid dispersions which neglect the Principle are briefly discussed. MD methods avoid the limitations of the Poisson-Bolzmann equation. Theoretical models which include the non-electrostatic components of the inter-ion and ion-surface interactions in solutions and colloid systems assume the additivity of dispersion and electrostatic forces. An experimental procedure to test this assumption is identified from the thermodynamics of condensers at microscopic plate separations. The available experimental data from Kelvin probe studies are preliminary, but tend against additivity. A corollary to the Gibbs-Guggenheim Principle is enunciated, and the Principle is restated that for any charged species, neither the difference in electrostatic potential nor the sum of the differences in the non-electrostatic components of the thermodynamic potential difference between regions of different chemical compositions can be measured." @default.
• W2145408077 created "2016-06-24" @default.
• W2145408077 creator A5019908428 @default.
• W2145408077 date "2007-01-01" @default.
• W2145408077 modified "2023-09-27" @default.
• W2145408077 title "Are electrostatic potentials between regions of different chemical composition measurable? The Gibbs–Guggenheim principle reconsidered, extended and its consequences revisited" @default.
• W2145408077 cites W1964670138 @default.
• W2145408077 cites W1967068862 @default.
• W2145408077 cites W1968003297 @default.
• W2145408077 cites W1982965138 @default.
• W2145408077 cites W1987153467 @default.
• W2145408077 cites W1992112369 @default.
• W2145408077 cites W2002051372 @default.
• W2145408077 cites W2008599149 @default.
• W2145408077 cites W2027344293 @default.
• W2145408077 cites W2036139268 @default.
• W2145408077 cites W2045593330 @default.
• W2145408077 cites W2054748631 @default.
• W2145408077 cites W2064756274 @default.
• W2145408077 cites W2068220866 @default.
• W2145408077 cites W2071103186 @default.
• W2145408077 cites W2072120795 @default.
• W2145408077 cites W2073870395 @default.
• W2145408077 cites W2075602647 @default.
• W2145408077 cites W2076952895 @default.
• W2145408077 cites W2077251768 @default.
• W2145408077 cites W2080902625 @default.
• W2145408077 cites W2083443234 @default.
• W2145408077 cites W2083830310 @default.
• W2145408077 cites W2129376238 @default.
• W2145408077 cites W2152607072 @default.
• W2145408077 cites W2155113527 @default.
• W2145408077 cites W2222762772 @default.
• W2145408077 cites W2281926759 @default.
• W2145408077 cites W2313875397 @default.
• W2145408077 cites W2331621503 @default.
• W2145408077 cites W2984994146 @default.
• W2145408077 cites W4210957215 @default.
• W2145408077 cites W2007158387 @default.
• W2145408077 doi "https://doi.org/10.1039/b706153f" @default.
• W2145408077 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18046474" @default.
• W2145408077 hasPublicationYear "2007" @default.
• W2145408077 type Work @default.
• W2145408077 sameAs 2145408077 @default.
• W2145408077 citedByCount "33" @default.
• W2145408077 countsByYear W21454080772012 @default.
• W2145408077 countsByYear W21454080772014 @default.
• W2145408077 countsByYear W21454080772015 @default.
• W2145408077 countsByYear W21454080772016 @default.
• W2145408077 countsByYear W21454080772017 @default.
• W2145408077 countsByYear W21454080772018 @default.
• W2145408077 countsByYear W21454080772019 @default.
• W2145408077 countsByYear W21454080772020 @default.
• W2145408077 countsByYear W21454080772021 @default.
• W2145408077 countsByYear W21454080772023 @default.
• W2145408077 crossrefType "journal-article" @default.
• W2145408077 hasAuthorship W2145408077A5019908428 @default.
• W2145408077 hasConcept C105795698 @default.
• W2145408077 hasConcept C109757611 @default.
• W2145408077 hasConcept C117626034 @default.
• W2145408077 hasConcept C121332964 @default.
• W2145408077 hasConcept C121864883 @default.
• W2145408077 hasConcept C145148216 @default.
• W2145408077 hasConcept C146477669 @default.
• W2145408077 hasConcept C147789679 @default.
• W2145408077 hasConcept C170961132 @default.
• W2145408077 hasConcept C17525397 @default.
• W2145408077 hasConcept C178790620 @default.
• W2145408077 hasConcept C184651966 @default.
• W2145408077 hasConcept C185592680 @default.
• W2145408077 hasConcept C19499675 @default.
• W2145408077 hasConcept C28556851 @default.
• W2145408077 hasConcept C33923547 @default.
• W2145408077 hasConcept C68801617 @default.
• W2145408077 hasConcept C73051877 @default.
• W2145408077 hasConcept C97355855 @default.
• W2145408077 hasConceptScore W2145408077C105795698 @default.
• W2145408077 hasConceptScore W2145408077C109757611 @default.
• W2145408077 hasConceptScore W2145408077C117626034 @default.
• W2145408077 hasConceptScore W2145408077C121332964 @default.
• W2145408077 hasConceptScore W2145408077C121864883 @default.
• W2145408077 hasConceptScore W2145408077C145148216 @default.
• W2145408077 hasConceptScore W2145408077C146477669 @default.
• W2145408077 hasConceptScore W2145408077C147789679 @default.
• W2145408077 hasConceptScore W2145408077C170961132 @default.
• W2145408077 hasConceptScore W2145408077C17525397 @default.
• W2145408077 hasConceptScore W2145408077C178790620 @default.
• W2145408077 hasConceptScore W2145408077C184651966 @default.
• W2145408077 hasConceptScore W2145408077C185592680 @default.
• W2145408077 hasConceptScore W2145408077C19499675 @default.
• W2145408077 hasConceptScore W2145408077C28556851 @default.
• W2145408077 hasConceptScore W2145408077C33923547 @default.
• W2145408077 hasConceptScore W2145408077C68801617 @default.
• W2145408077 hasConceptScore W2145408077C73051877 @default.
• W2145408077 hasConceptScore W2145408077C97355855 @default.
• W2145408077 hasIssue "47" @default.
• W2145408077 hasLocation W21454080771 @default.
• W2145408077 hasLocation W21454080772 @default.

• next