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- W2145605621 abstract "Abstract Clathrate hydrate slurries are promising systems in the field of cold distribution. In this work, the L w ‐H‐V equilibrium conditions, the dissociation enthalpy, and the CO 2 hydration number of a clathrate hydrate formed from THF/CO 2 /water mixtures were studied, using a DSC method. For equilibrium condition determination, THF concentration was varied from 1.0 to 16.0 wt % and CO 2 partial pressure range was 0.2 to 2.0 MPa. For enthalpy measurements, THF concentration was fixed at 19 wt % and CO 2 partial pressure investigated from 0.2 to 2.0 MPa. Experimental equilibrium temperatures and enthalpy values were in good agreement with the results of a model combining the van der Waals and Platteeuw approach with the RKS equation of state associated to a MHV2 mixing rule and UNIFAC model. Equilibrium conditions and dissociation enthalpy show that THF + CO 2 hydrate slurries are promising mixtures for refrigeration application. © 2008 American Institute of Chemical Engineers AIChE J, 2008" @default.
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- W2145605621 date "2008-02-29" @default.
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- W2145605621 title "Thermodynamic properties of THF + CO2 hydrates in relation with refrigeration applications" @default.
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- W2145605621 doi "https://doi.org/10.1002/aic.11455" @default.
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