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• W2145678049 startingPage "413" @default.
• W2145678049 abstract "Abstract The production, isolation, and spectroscopic characterization of a new Dy 3 N@C 80 cluster fullerene that exhibits three isomers ( 1 – 3 ) is reported for the first time. In addition, the third isomer ( 3 ) forms a completely new C 80 cage structure that has not been reported in any endohedral fullerenes so far. The isomeric structures of the Dy 3 N@C 80 cluster fullerene were analyzed by studying HPLC retention behavior, laser desorption time‐of‐flight (LD‐TOF) mass spectrometry, and UV‐Vis‐NIR and FTIR spectroscopy. The three isomers of Dy 3 N@C 80 were all large band‐gap (1.51, 1.33, and 1.31 eV for 1 – 3 , respectively) materials, and could be classified as very stable fullerenes. According to results of FTIR spectroscopy, the Dy 3 N@C 80 (I) ( 1 ) was assigned to the fullerene cage C 80 :7 ( I h ), whereas Dy 3 N@C 80 (II) ( 2 ) had the cage structure of C 80 :6 ( D 5 h ). The most probable cage structure of Dy 3 N@C 80 (III) ( 3 ) was proposed to be C 80 :1 ( D 5 d ). The significant differences between Dy 3 N@C 80 and other reported M 3 N@C 80 (M=Sc, Y, Gd, Tb, Ho, Er, Tm) cluster fullerenes are discussed in detail, and the strong influence of the metal on the nitride cluster fullerene formation is concluded." @default.
• W2145678049 created "2016-06-24" @default.
• W2145678049 creator A5027903798 @default.
• W2145678049 creator A5034497746 @default.
• W2145678049 date "2005-12-19" @default.
• W2145678049 modified "2023-10-18" @default.
• W2145678049 title "Expanding the Number of Stable Isomeric Structures of the C80 Cage: A New Fullerene Dy3N@C80" @default.
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• W2145678049 doi "https://doi.org/10.1002/chem.200500383" @default.
• W2145678049 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16224762" @default.
• W2145678049 hasPublicationYear "2005" @default.
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