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- W2145720106 abstract "The solubility of paracetamol was determined as a function of temperature in mixtures of wide polarity range (ethyl acetate:ethanol and ethanol:water) to compare the solvation effects of amphiprotic and amphiprotic-aprotic solvent systems.The mole fraction solubility of the drug showed solubility maxima at δ1 = 14·53 (cal mL−1)1/2 (15:85 v/v, water:ethanol) and δ1 = 11·78 (cal mL−1)1/2 (30:70 v/v, ethyl acetate:ethanol) against the solubility parameter (δ1) of these solvent mixtures. The solubility peaks result from different processes, and the nature of the solvent mixture plays an important role; in the ethanol:water mixtures, the dissolution process is entropy-controlled while enthalpy is the driving force in the case of ethanol:ethyl acetate mixtures. The nature of the solute determines the solvent proportion at which the solubility peak is located in the amphiprotic-aprotic mixture.Separate nonlinear enthalpy-entropy compensation is observed in the two solvent systems. Ethanol deviates from the general trend in the amphiprotic mixtures." @default.
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- W2145720106 date "1995-11-01" @default.
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- W2145720106 title "Thermodynamics of Paracetamol in Amphiprotic and Amphiprotic—aprotic Solvent Mixtures" @default.
- W2145720106 doi "https://doi.org/10.1111/j.2042-7158.1995.tb00366.x" @default.
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