Matches in SemOpenAlex for { <https://semopenalex.org/work/W2145732016> ?p ?o ?g. }
- W2145732016 endingPage "5545" @default.
- W2145732016 startingPage "5540" @default.
- W2145732016 abstract "Abstract Homoannularly bridged ferrocene 6b was prepared by intramolecular coupling of 1,5‐dilithioferrocene 5b mediated by Fe(acac) 3 . Dilithioferrocene 5b was prepared by lithium–halogen exchange of the corresponding diiodide, which was prepared by 1,5‐dilithiation of the o ‐TMS‐blocked ferrocene and followed by trapping with iodine and removal of the TMS group. Alternatively, 5b could be readily prepared by the reaction of o ‐bromophenylferrocene 8 with n BuLi (>2 equiv.). The benzene ring of 6b underwent ortho lithiation with t BuLi, and the resulting lithiated species was trapped with Ph 2 PCl to produce corresponding aminophosphane 7d . Aminophosphane 13 , which has the phosphanyl group on the cyclopentadienyl ring, was prepared by intramolecular coupling of 1,5‐dilithiated PhPPFA 11 mediated by Fe(acac) 3 . New N,P ligands 7d and 13 were used in the palladium‐catalyzed allylic alkylation and amination of 1,3‐diphenyl‐2‐propenyl acetate ( 14 ), and ligand 7d was found to give good yields with enantioselectivities as high as 96 % ee . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2145732016 created "2016-06-24" @default.
- W2145732016 creator A5008790464 @default.
- W2145732016 creator A5015983638 @default.
- W2145732016 creator A5037982236 @default.
- W2145732016 creator A5077785875 @default.
- W2145732016 date "2007-10-30" @default.
- W2145732016 modified "2023-10-11" @default.
- W2145732016 title "Preparation of Chiral Homoannularly Bridged N,P‐Ferrocenyl Ligands by Intramolecular Coupling of 1,5‐Dilithioferrocenes and Their Application in Asymmetric Allylic Substitution Reactions" @default.
- W2145732016 cites W1965190664 @default.
- W2145732016 cites W1967111166 @default.
- W2145732016 cites W1967908946 @default.
- W2145732016 cites W1974292676 @default.
- W2145732016 cites W1979350834 @default.
- W2145732016 cites W1983485571 @default.
- W2145732016 cites W1985650838 @default.
- W2145732016 cites W1986336131 @default.
- W2145732016 cites W1989873766 @default.
- W2145732016 cites W1997260045 @default.
- W2145732016 cites W2004202780 @default.
- W2145732016 cites W2005585217 @default.
- W2145732016 cites W2008372267 @default.
- W2145732016 cites W2011044207 @default.
- W2145732016 cites W2021894635 @default.
- W2145732016 cites W2025478304 @default.
- W2145732016 cites W2025539974 @default.
- W2145732016 cites W2029584505 @default.
- W2145732016 cites W2037519764 @default.
- W2145732016 cites W2043121450 @default.
- W2145732016 cites W2047755968 @default.
- W2145732016 cites W2059345419 @default.
- W2145732016 cites W2059880114 @default.
- W2145732016 cites W2064846751 @default.
- W2145732016 cites W2076694590 @default.
- W2145732016 cites W2083545872 @default.
- W2145732016 cites W2084533471 @default.
- W2145732016 cites W2084696737 @default.
- W2145732016 cites W2092128460 @default.
- W2145732016 cites W2093224815 @default.
- W2145732016 cites W2094048001 @default.
- W2145732016 cites W2099358996 @default.
- W2145732016 cites W2102460951 @default.
- W2145732016 cites W2103214112 @default.
- W2145732016 cites W2107386828 @default.
- W2145732016 cites W2107692241 @default.
- W2145732016 cites W2111668130 @default.
- W2145732016 cites W2114424373 @default.
- W2145732016 cites W2143568619 @default.
- W2145732016 cites W2152668042 @default.
- W2145732016 cites W2172388433 @default.
- W2145732016 cites W2174040555 @default.
- W2145732016 cites W2336887534 @default.
- W2145732016 cites W2498418350 @default.
- W2145732016 cites W4237525037 @default.
- W2145732016 cites W4252675871 @default.
- W2145732016 doi "https://doi.org/10.1002/ejoc.200700470" @default.
- W2145732016 hasPublicationYear "2007" @default.
- W2145732016 type Work @default.
- W2145732016 sameAs 2145732016 @default.
- W2145732016 citedByCount "35" @default.
- W2145732016 countsByYear W21457320162012 @default.
- W2145732016 countsByYear W21457320162013 @default.
- W2145732016 countsByYear W21457320162014 @default.
- W2145732016 countsByYear W21457320162016 @default.
- W2145732016 countsByYear W21457320162017 @default.
- W2145732016 countsByYear W21457320162019 @default.
- W2145732016 countsByYear W21457320162023 @default.
- W2145732016 crossrefType "journal-article" @default.
- W2145732016 hasAuthorship W2145732016A5008790464 @default.
- W2145732016 hasAuthorship W2145732016A5015983638 @default.
- W2145732016 hasAuthorship W2145732016A5037982236 @default.
- W2145732016 hasAuthorship W2145732016A5077785875 @default.
- W2145732016 hasConcept C111185830 @default.
- W2145732016 hasConcept C116569031 @default.
- W2145732016 hasConcept C120095180 @default.
- W2145732016 hasConcept C147789679 @default.
- W2145732016 hasConcept C155647269 @default.
- W2145732016 hasConcept C161790260 @default.
- W2145732016 hasConcept C170493617 @default.
- W2145732016 hasConcept C17525397 @default.
- W2145732016 hasConcept C178790620 @default.
- W2145732016 hasConcept C181458950 @default.
- W2145732016 hasConcept C185592680 @default.
- W2145732016 hasConcept C198503264 @default.
- W2145732016 hasConcept C27083343 @default.
- W2145732016 hasConcept C2777237805 @default.
- W2145732016 hasConcept C2780378348 @default.
- W2145732016 hasConcept C502130503 @default.
- W2145732016 hasConcept C52859227 @default.
- W2145732016 hasConcept C55493867 @default.
- W2145732016 hasConcept C71240020 @default.
- W2145732016 hasConcept C75079739 @default.
- W2145732016 hasConceptScore W2145732016C111185830 @default.
- W2145732016 hasConceptScore W2145732016C116569031 @default.
- W2145732016 hasConceptScore W2145732016C120095180 @default.
- W2145732016 hasConceptScore W2145732016C147789679 @default.
- W2145732016 hasConceptScore W2145732016C155647269 @default.
- W2145732016 hasConceptScore W2145732016C161790260 @default.