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- W2145950447 abstract "The following structures for the two new genins G and H from Sarcostemma viminale have been deduced. Genin G is shown to be 12-O-benzoyl-deacetylmetaplcxigenin (3). On the basis of physical data, its behaviour in KOH-methanol solution and its positive test with alcaline silver-diammine solution, the structure of 3β, 8β, 14β, 17β-tetrahydroxy-12β, 21-dibenzoyloxy-20-oxo-17α-pregn-5-ene (4) is proposed for genin H. This substance therefore contains a dihydroxyacetone group like some corticoids (e.g. Cortisol), but with different stereochemistry at C-14 and C-17." @default.
- W2145950447 created "2016-06-24" @default.
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- W2145950447 date "1968-04-01" @default.
- W2145950447 modified "2023-10-07" @default.
- W2145950447 title "Die Struktur der Genine G (12-O-Benzoyl-desacetylmetaplexigenin) und H (Di-O-benzoyl-viminolon) aus den Stengeln von Sarcostemma viminale (L.) R.Br.: Glykoside und Aglykone 308. Mitteilung" @default.
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- W2145950447 doi "https://doi.org/10.1002/hlca.660510417" @default.
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