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- W2145957381 abstract "Abstract Although quinone methides are often postulated as intermediates in the biosynthesis of many polyphenolic natural products, deploying their power in a laboratory setting to achieve similar bond constructions has sometimes proven challenging. Herein, a total synthesis of the resveratrol trimer vaticanol A has been achieved through three instances of quinone methide chemistry. These operations, one of which succeeded only under very specific conditions, expediently generated its [7,5]‐carbocyclic core, afforded a unique sequence for dihydrobenzofuran formation, and concurrently generated, in addition to the target molecule, a series of diastereomers reflective of many other isolates." @default.
- W2145957381 created "2016-06-24" @default.
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- W2145957381 date "2014-05-19" @default.
- W2145957381 modified "2023-10-18" @default.
- W2145957381 title "Harnessing Quinone Methides: Total Synthesis of (±)-Vaticanol A" @default.
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- W2145957381 doi "https://doi.org/10.1002/anie.201402858" @default.
- W2145957381 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4106016" @default.
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