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- W2146023871 abstract "The infrared spectra (1050-150 cm−1) of the complexes [M(dmso)6](ClO4)2 (dmso = dimethylsulphoxide; M = Mn, Co, Ni, Zn) [M(dmso)6](ClO4)3 (M = Sc, Fe, Ga) and [Cu(dmso)n](ClO4)2 (n = 4, 5, 6) are discussed. Assignments of ligand and metal—ligand vibrations are based on the band shifts induced by 18O-labelling of the oxygen donors, by deuteration of the methyl groups and by the effects of metal ion substitution. On the assumption of Oh site-symmetry for all the complexes except those of Cu(II), one ν(MO) band is expected and observed. The spectra of the 4-, 5- and 6-coordinate Cu(II) complexes are rationalized on the basis of D4h square-planar, C4v square-pyramidal and D4h tetragonal coordination, respectively." @default.
- W2146023871 created "2016-06-24" @default.
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- W2146023871 date "1979-01-01" @default.
- W2146023871 modified "2023-09-27" @default.
- W2146023871 title "The infrared spectra of dimethylsulphoxide complexes of transition metal perchlorates: band assignments by isotopic labelling and structural aspects of the spectra" @default.
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- W2146023871 doi "https://doi.org/10.1016/0022-2860(79)80092-7" @default.
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