Matches in SemOpenAlex for { <https://semopenalex.org/work/W2146028179> ?p ?o ?g. }
- W2146028179 endingPage "6799" @default.
- W2146028179 startingPage "6795" @default.
- W2146028179 abstract "Abstract We report the first general synthesis of boron‐substituted monobenzofused 1,4‐azaborines using ring‐closing metathesis of an enamine‐containing diene as a key synthetic strategy. As part of our investigations, we discovered that the B‐C3 moiety in a 1,4‐azaborine can serve uniquely as a η 2 ‐L‐type ligand. This functionality is exemplified by two κ 2 ‐ N ‐η 2 ‐BC Pt complexes of a boron‐pyridyl‐substituted monobenzofused‐1,4‐azaborine. Single‐crystal X‐ray diffraction analysis of the Pt complexes shows a strong structural contribution from the iminium resonance form of the monobenzofused‐1,4‐azaborine ligand. We also demonstrate that a palladium(0) complex supported by a 1,4‐azaborine‐based phosphine ligand can catalyze hydroboration of 1‐buten‐3‐yne with unique selectivity. In view of the importance of arene–metal π‐interactions in catalytic applications, this work should open new opportunities for ligand design involving the 1,4‐azaborine motif as an arene substitute." @default.
- W2146028179 created "2016-06-24" @default.
- W2146028179 creator A5006493143 @default.
- W2146028179 creator A5034995105 @default.
- W2146028179 creator A5051922492 @default.
- W2146028179 creator A5061022125 @default.
- W2146028179 creator A5084999737 @default.
- W2146028179 date "2014-05-18" @default.
- W2146028179 modified "2023-10-18" @default.
- W2146028179 title "Monobenzofused 1,4-Azaborines: Synthesis, Characterization, and Discovery of a Unique Coordination Mode" @default.
- W2146028179 cites W1964038229 @default.
- W2146028179 cites W1966179075 @default.
- W2146028179 cites W1968964929 @default.
- W2146028179 cites W1974267266 @default.
- W2146028179 cites W1975941566 @default.
- W2146028179 cites W1977855843 @default.
- W2146028179 cites W1978028948 @default.
- W2146028179 cites W1983155558 @default.
- W2146028179 cites W1983794742 @default.
- W2146028179 cites W1988713671 @default.
- W2146028179 cites W2002482043 @default.
- W2146028179 cites W2003373590 @default.
- W2146028179 cites W2003710381 @default.
- W2146028179 cites W2006015450 @default.
- W2146028179 cites W2006372390 @default.
- W2146028179 cites W2006444373 @default.
- W2146028179 cites W2010735635 @default.
- W2146028179 cites W2012463045 @default.
- W2146028179 cites W2014907576 @default.
- W2146028179 cites W2015904059 @default.
- W2146028179 cites W2029329406 @default.
- W2146028179 cites W2030087348 @default.
- W2146028179 cites W2030841140 @default.
- W2146028179 cites W2042679140 @default.
- W2146028179 cites W2048520333 @default.
- W2146028179 cites W2049856758 @default.
- W2146028179 cites W2056767734 @default.
- W2146028179 cites W2057213036 @default.
- W2146028179 cites W2079328276 @default.
- W2146028179 cites W2080031224 @default.
- W2146028179 cites W2100792227 @default.
- W2146028179 cites W2106837604 @default.
- W2146028179 cites W2107048483 @default.
- W2146028179 cites W2116130142 @default.
- W2146028179 cites W2116884775 @default.
- W2146028179 cites W2123177357 @default.
- W2146028179 cites W2126383912 @default.
- W2146028179 cites W2126582057 @default.
- W2146028179 cites W2130472598 @default.
- W2146028179 cites W2131064423 @default.
- W2146028179 cites W2132062372 @default.
- W2146028179 cites W2142987413 @default.
- W2146028179 cites W2144821086 @default.
- W2146028179 cites W2148387188 @default.
- W2146028179 cites W2148517659 @default.
- W2146028179 cites W2151635324 @default.
- W2146028179 cites W2158093973 @default.
- W2146028179 cites W2158492314 @default.
- W2146028179 cites W2158705142 @default.
- W2146028179 cites W2158705565 @default.
- W2146028179 cites W2161090794 @default.
- W2146028179 cites W2163413179 @default.
- W2146028179 cites W2328035966 @default.
- W2146028179 cites W2332174563 @default.
- W2146028179 cites W2950735072 @default.
- W2146028179 cites W2951518983 @default.
- W2146028179 cites W2952393861 @default.
- W2146028179 cites W4205119539 @default.
- W2146028179 cites W4210604151 @default.
- W2146028179 cites W4233714252 @default.
- W2146028179 cites W4237228781 @default.
- W2146028179 cites W4245269574 @default.
- W2146028179 cites W4245566798 @default.
- W2146028179 cites W4245630418 @default.
- W2146028179 doi "https://doi.org/10.1002/anie.201403903" @default.
- W2146028179 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24838444" @default.
- W2146028179 hasPublicationYear "2014" @default.
- W2146028179 type Work @default.
- W2146028179 sameAs 2146028179 @default.
- W2146028179 citedByCount "67" @default.
- W2146028179 countsByYear W21460281792014 @default.
- W2146028179 countsByYear W21460281792015 @default.
- W2146028179 countsByYear W21460281792016 @default.
- W2146028179 countsByYear W21460281792017 @default.
- W2146028179 countsByYear W21460281792018 @default.
- W2146028179 countsByYear W21460281792019 @default.
- W2146028179 countsByYear W21460281792020 @default.
- W2146028179 countsByYear W21460281792021 @default.
- W2146028179 countsByYear W21460281792022 @default.
- W2146028179 countsByYear W21460281792023 @default.
- W2146028179 crossrefType "journal-article" @default.
- W2146028179 hasAuthorship W2146028179A5006493143 @default.
- W2146028179 hasAuthorship W2146028179A5034995105 @default.
- W2146028179 hasAuthorship W2146028179A5051922492 @default.
- W2146028179 hasAuthorship W2146028179A5061022125 @default.
- W2146028179 hasAuthorship W2146028179A5084999737 @default.
- W2146028179 hasConcept C116569031 @default.
- W2146028179 hasConcept C153914509 @default.