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- W2146039786 abstract "With the guidance of ab initio computations, the microwave spectra of the axial and equatorial conformers of cyclobutyl acetylene have been identified and assigned. Dipole moment measurements yielded μa=0.82(1) and μc=0.09(2) D for the equatorial conformer and μa=0.79(1) D and μc=0.13(2) D for the axial conformer. Relative intensity measurements showed that the equatorial conformer was more stable by 282±35 cm−1. By combining ab initio results with the experimental rotational constants, the structures of the two conformers have been determined with a reliability and precision greater than possible from either method alone." @default.
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- W2146039786 date "1988-10-01" @default.
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- W2146039786 title "The structures, dipole moments and relative energy of the conformers of cyclobutyl acetylene by microwave and ab initio methods" @default.
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- W2146039786 doi "https://doi.org/10.1016/0022-2860(88)80208-4" @default.
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