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- W2146117934 abstract "Polymerization of 1,3-butadiene with the CoBr 2 (PPh 3 ) 2 /MgCl 2 /SiPh 2 (OCH 3 ) 2 -Al(CH 3 ) 3 catalyst system was conducted in the presence of ethylene. It was found that addition of ethylene causes a marked decrease in the molecular weight of polybutadiene although ethylene is not incorporated at the chain end. The structure of chain ends was analyzed using very low molecular weight polybutadiene produced in the presence of ethylene, which led to the conclusion that 1,2 and 2,1 insertion reactions predominate at the initiation and propagation steps, respectively" @default.
- W2146117934 created "2016-06-24" @default.
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- W2146117934 date "1995-03-01" @default.
- W2146117934 modified "2023-09-25" @default.
- W2146117934 title "Structure of chain-ends in polybutadiene produced with the CoBr2(PPh3)2/MgCl2/SiPh2(OCH3)2-Al(CH3)3 catalyst system" @default.
- W2146117934 doi "https://doi.org/10.1002/marc.1995.030160303" @default.
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