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- W2146164012 abstract "1H,2H-Hexafluorocyclohexa-1,3-diene (1) dimerizes slowly at room temperature; with perfluorobut-2-yne and 3,3,3-trifluoropropyne at 200° the diene (1) gives 2,3-bis(trifluoromethyl)-1,6,7,7,8,8-hexafluorobicyclo[2,2,2]-octa-2,5-diene (5) and 2-trifluoromethyl-4,5,7,7,8,8-hexafluorobicyclo[2,2,2]octa-2,5-diene (4) respectively, together with dimer. Pyrolysis of (4) gives 3,4-difluorobenzotrifluoride which was also prepared from 3-amino-4-fluorobenzotrifluoride by way of pyrolysis of the diazonium tetrafluoroborate." @default.
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- W2146164012 date "1971-01-01" @default.
- W2146164012 modified "2023-09-26" @default.
- W2146164012 title "Diels–Alder reactions of polyfluorocyclohexa-1,3-dienes. Part IV. Addition of alkynes to 1H,2H-hexafluorocyclohexa-1,3-diene" @default.
- W2146164012 doi "https://doi.org/10.1039/j39710001547" @default.
- W2146164012 hasPublicationYear "1971" @default.
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