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- W2146164524 abstract "Spectral fingerprints: Collision-induced dissociation (CID) of protonated peptides in the gas phase results in linear fragment ions with a five-membered oxazolone ring on their C-terminal side. Infrared spectroscopy confirms that smaller fragments adopt oxazolone structures. Conversely, in mid-sized and larger fragments an isomerization to “head-to-tail” macrocycles is observed (see picture). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2146164524 date "2012-05-22" @default.
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- W2146164524 title "Defying Entropy: Forming Large Head-to-Tail Macrocycles in the Gas Phase" @default.
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- W2146164524 doi "https://doi.org/10.1002/anie.201202405" @default.
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