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• W2146255740 abstract "Simple reactions between Re(CO)5Cl and 2-benzoxazol-2-ylphenol, 2-benzothiazol-2-ylphenol or 2-(1-methyl-1H- benzoimidazol-2-yl)phenol (performed in boiling toluene) lead to dimeric complexes of general formula Re2(CO)6(N∩O−)2. The obtained dimeric species are quite stable in non-coordinating solvents, but in coordinating media (e.g., pyridine – pyr) they undergo disscociative solvolysis to form monomeric derivatives of general formula Re(CO)3(N∩O−)pyr. Molecular structures of both the dimeric and monomeric forms have been confirmed by means of X-ray measurements, electron impact mass spectrometry and IR spectroscopic investigations. UV-VIS absorption and emission properties of the newly synthesized Re(CO)3+ complexes have been investigated and briefly compared with those previously reported for their 8-oxyquinolinato analogues." @default.
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• W2146255740 date "2002-01-01" @default.
• W2146255740 modified "2023-09-23" @default.
• W2146255740 title "Re^I(CO)₃⁺complexes with N∩O⁻bidentate ligands" @default.
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• W2146255740 doi "https://doi.org/10.1039/b204020d" @default.
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