FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2146307154> ?p ?o ?g. }

• W2146307154 endingPage "654" @default.
• W2146307154 startingPage "645" @default.
• W2146307154 abstract "Abstract The addition of propagating radicals of methyl acrylate (MA) and styrene (St) to CH 2 C(CO 2 CH 3 )CH 2  and CH 2 C(C 6 H 5 )CH 2  ω‐end groups of poly(methyl methacrylate) (PMMA) and polystyrene (PSt) was investigated. The end groups were as reactive as MA and St toward the poly(methyl acrylate) (PMA) and PSt radicals, respectively. The adduct radical derived from the two types of PMMA end groups and PMA radicals underwent β fragmentation exclusively to yield PMMA radicals and end groups bound to PMA chains. The addition of PSt radicals to PMMA with CH 2 C(CO 2 Me)CH 2  end groups resulted in adduct radicals that underwent β fragmentation and addition to St or coupling with PSt radicals. Adduct radicals formed by the addition of PMA radicals to both types of end groups of PSt exclusively formed CC bond by coupling with PMA radicals to form branched structures or by addition to MA monomer to give a copolymer. The fate of the adduct radicals was highly dependent on the type of polymer chain and the substituent bound to the end group. Steric congestion of the adduct radical arising from the α‐methyl group of the PMMA chain was considered to be crucial for fragmentation to expel the PMMA radical. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 645–654, 2003" @default.
• W2146307154 created "2016-06-24" @default.
• W2146307154 creator A5028335653 @default.
• W2146307154 creator A5057704685 @default.
• W2146307154 creator A5085030085 @default.
• W2146307154 date "2003-01-16" @default.
• W2146307154 modified "2023-10-17" @default.
• W2146307154 title "Substituted propenyl end groups as reactive intermediates in radical polymerization" @default.
• W2146307154 cites W1964108066 @default.
• W2146307154 cites W1974383573 @default.
• W2146307154 cites W1978518147 @default.
• W2146307154 cites W1980103013 @default.
• W2146307154 cites W1981956308 @default.
• W2146307154 cites W1984694373 @default.
• W2146307154 cites W1985829407 @default.
• W2146307154 cites W2010742388 @default.
• W2146307154 cites W2015027587 @default.
• W2146307154 cites W2052853068 @default.
• W2146307154 cites W2068062834 @default.
• W2146307154 cites W2070330352 @default.
• W2146307154 cites W2073126954 @default.
• W2146307154 cites W2074340802 @default.
• W2146307154 cites W2084584404 @default.
• W2146307154 cites W2085404335 @default.
• W2146307154 doi "https://doi.org/10.1002/pola.10587" @default.
• W2146307154 hasPublicationYear "2003" @default.
• W2146307154 type Work @default.
• W2146307154 sameAs 2146307154 @default.
• W2146307154 citedByCount "39" @default.
• W2146307154 countsByYear W21463071542013 @default.
• W2146307154 countsByYear W21463071542014 @default.
• W2146307154 countsByYear W21463071542016 @default.
• W2146307154 countsByYear W21463071542017 @default.
• W2146307154 countsByYear W21463071542018 @default.
• W2146307154 countsByYear W21463071542019 @default.
• W2146307154 countsByYear W21463071542021 @default.
• W2146307154 countsByYear W21463071542022 @default.
• W2146307154 countsByYear W21463071542023 @default.
• W2146307154 crossrefType "journal-article" @default.
• W2146307154 hasAuthorship W2146307154A5028335653 @default.
• W2146307154 hasAuthorship W2146307154A5057704685 @default.
• W2146307154 hasAuthorship W2146307154A5085030085 @default.
• W2146307154 hasBestOaLocation W21463071541 @default.
• W2146307154 hasConcept C108204754 @default.
• W2146307154 hasConcept C139066938 @default.
• W2146307154 hasConcept C152236973 @default.
• W2146307154 hasConcept C155647269 @default.
• W2146307154 hasConcept C15920480 @default.
• W2146307154 hasConcept C166940927 @default.
• W2146307154 hasConcept C178790620 @default.
• W2146307154 hasConcept C185592680 @default.
• W2146307154 hasConcept C188027245 @default.
• W2146307154 hasConcept C201194858 @default.
• W2146307154 hasConcept C2777566558 @default.
• W2146307154 hasConcept C2777935641 @default.
• W2146307154 hasConcept C2778004933 @default.
• W2146307154 hasConcept C2778248756 @default.
• W2146307154 hasConcept C2778689049 @default.
• W2146307154 hasConcept C44228677 @default.
• W2146307154 hasConcept C521977710 @default.
• W2146307154 hasConcept C71240020 @default.
• W2146307154 hasConcept C75473681 @default.
• W2146307154 hasConceptScore W2146307154C108204754 @default.
• W2146307154 hasConceptScore W2146307154C139066938 @default.
• W2146307154 hasConceptScore W2146307154C152236973 @default.
• W2146307154 hasConceptScore W2146307154C155647269 @default.
• W2146307154 hasConceptScore W2146307154C15920480 @default.
• W2146307154 hasConceptScore W2146307154C166940927 @default.
• W2146307154 hasConceptScore W2146307154C178790620 @default.
• W2146307154 hasConceptScore W2146307154C185592680 @default.
• W2146307154 hasConceptScore W2146307154C188027245 @default.
• W2146307154 hasConceptScore W2146307154C201194858 @default.
• W2146307154 hasConceptScore W2146307154C2777566558 @default.
• W2146307154 hasConceptScore W2146307154C2777935641 @default.
• W2146307154 hasConceptScore W2146307154C2778004933 @default.
• W2146307154 hasConceptScore W2146307154C2778248756 @default.
• W2146307154 hasConceptScore W2146307154C2778689049 @default.
• W2146307154 hasConceptScore W2146307154C44228677 @default.
• W2146307154 hasConceptScore W2146307154C521977710 @default.
• W2146307154 hasConceptScore W2146307154C71240020 @default.
• W2146307154 hasConceptScore W2146307154C75473681 @default.
• W2146307154 hasIssue "5" @default.
• W2146307154 hasLocation W21463071541 @default.
• W2146307154 hasOpenAccess W2146307154 @default.
• W2146307154 hasPrimaryLocation W21463071541 @default.
• W2146307154 hasRelatedWork W1532011346 @default.
• W2146307154 hasRelatedWork W1992238089 @default.
• W2146307154 hasRelatedWork W1996245498 @default.
• W2146307154 hasRelatedWork W1999552447 @default.
• W2146307154 hasRelatedWork W2003230977 @default.
• W2146307154 hasRelatedWork W2031016979 @default.
• W2146307154 hasRelatedWork W2074284934 @default.
• W2146307154 hasRelatedWork W2147989924 @default.
• W2146307154 hasRelatedWork W2327868647 @default.
• W2146307154 hasRelatedWork W2764546461 @default.
• W2146307154 hasVolume "41" @default.
• W2146307154 isParatext "false" @default.
• W2146307154 isRetracted "false" @default.

• next