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• W2146348306 abstract "Blends of AB-diblock copolymers and C-homopolymers (AB/C), in which A and C are capable of forming hydrogen bonds, are used as a model system to examine and validate two approaches for modeling the effects of hydrogen bonding on the phase behavior of polymeric systems. The first model assumes a negative Flory–Huggins parameter between the A/C monomers. This attractive-interaction model reproduces qualitatively correct phase transition sequences as compared with experiments, but it fails to correctly describe the change of lamellar spacing induced by the addition of the C-homopolymers. The second model assumes that hydrogen bonding leads to A/C complexation. The interpolymer-complexation model predicts correctly the order–order phase transition sequences and the decrease of lamellar spacing at strong hydrogen bonding. The results demonstrate that hydrogen bonding of polymers should be modeled by the interpolymer-complexation model." @default.
• W2146348306 created "2016-06-24" @default.
• W2146348306 creator A5005451828 @default.
• W2146348306 creator A5046374024 @default.
• W2146348306 date "2013-07-09" @default.
• W2146348306 modified "2023-10-09" @default.
• W2146348306 title "Modeling Hydrogen Bonding in Diblock Copolymer/Homopolymer Blends" @default.
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• W2146348306 doi "https://doi.org/10.1021/ma4008576" @default.
• W2146348306 hasPublicationYear "2013" @default.
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