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- W2146353693 abstract "The enantiopure Davis' N-sulfinylimines were found to be efficient as chiral imine equivalents in the high-temperature Reformatsky-type additions with BrZnCF(2)COOEt affording an efficient approach to the enantiomerically pure alpha,alpha-difluoro-beta-amino acids. High chemical and stereochemical yields (drs > 9:1, and as high as 99:1) render this method immediately useful for preparing the target amino acids." @default.
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- W2146353693 date "2003-08-22" @default.
- W2146353693 modified "2023-10-16" @default.
- W2146353693 title "Convenient Asymmetric Synthesis of β-Substituted α,α-Difluoro-β-amino Acids via Reformatsky Reaction between Davis'<i>N</i>-Sulfinylimines and Ethyl Bromodifluoroacetate" @default.
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- W2146353693 doi "https://doi.org/10.1021/jo030082k" @default.
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