FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2146384580> ?p ?o ?g. }

• W2146384580 endingPage "401" @default.
• W2146384580 startingPage "391" @default.
• W2146384580 abstract "We have studied the reaction of ethylene with a group of [NiXRL2] complexes with R = 2,4,6-Me3C6H2, 3,5-Cl2C6H3, 2,3-Cl2C6H3, C6Cl5, or 2-MeC6H4 and L = mainly PPh3. Migratory insertion and β-elimination of vinyl or butenyl R products was observed, but only under ethylene pressure. The smallest activation energy for this reaction was observed with the complex containing 2,4,6-Me3C6H2. Detection of the hydride generated in these reactions has been attempted by formation of a metalacycle using [NiBr(2,4,6-Me3C6H2)(PPh2(CH2CH2CHCH2))2] as the starting complex. The direction of the insertion of propene into the NiR bond depends on the size of R. When R = mesityl, 100% of Ni → C2 compounds were obtained, whereas for R = 3,5-Cl2C6H3, 80% of Ni → C1 compounds were recovered. Many of the hydride species formed in the reactions of neutral and ionic mesityl derivatives [NiBr(2,4,6-Me3C6H2)L2] and [Ni(2,4,6-Me3C6H2)(CH3CN)L2]BF4 (L  PEt3, PMe2Ph, PPh3, P(nBu)3, P(iBu)3, PCy3, PBz3, dppe or PN(PPh2CH2(2-py)) with ethylene are able to catalyze the dimerization of ethylene. Bidentate ligands do not show any activity. The insertion of ethylene in the nickel—carbon bonds occurs after prior dissociation of a neutral ligand. The different selectivities are discussed." @default.
• W2146384580 created "2016-06-24" @default.
• W2146384580 creator A5016109186 @default.
• W2146384580 creator A5018178541 @default.
• W2146384580 creator A5052517822 @default.
• W2146384580 creator A5056951996 @default.
• W2146384580 creator A5084702465 @default.
• W2146384580 date "1992-05-01" @default.
• W2146384580 modified "2023-10-16" @default.
• W2146384580 title "Reactions of neutral and ionic square-planar organometallic nickel compounds with ethylene" @default.
• W2146384580 cites W1580606597 @default.
• W2146384580 cites W1967762784 @default.
• W2146384580 cites W1969262368 @default.
• W2146384580 cites W1998317631 @default.
• W2146384580 cites W2003162132 @default.
• W2146384580 cites W2004055530 @default.
• W2146384580 cites W2012165649 @default.
• W2146384580 cites W2018024714 @default.
• W2146384580 cites W2018361673 @default.
• W2146384580 cites W2023490293 @default.
• W2146384580 cites W2029118421 @default.
• W2146384580 cites W2034329598 @default.
• W2146384580 cites W2042388700 @default.
• W2146384580 cites W2043704912 @default.
• W2146384580 cites W2044940880 @default.
• W2146384580 cites W2055668701 @default.
• W2146384580 cites W2056125517 @default.
• W2146384580 cites W2059076004 @default.
• W2146384580 cites W2059783584 @default.
• W2146384580 cites W2064279286 @default.
• W2146384580 cites W2066893833 @default.
• W2146384580 cites W2074332422 @default.
• W2146384580 cites W2075514897 @default.
• W2146384580 cites W2081080419 @default.
• W2146384580 cites W2089662665 @default.
• W2146384580 cites W2092257054 @default.
• W2146384580 cites W2100472849 @default.
• W2146384580 cites W2157121890 @default.
• W2146384580 cites W2171152699 @default.
• W2146384580 cites W2344528362 @default.
• W2146384580 cites W253566285 @default.
• W2146384580 cites W2951861141 @default.
• W2146384580 cites W4232173500 @default.
• W2146384580 cites W2139424476 @default.
• W2146384580 doi "https://doi.org/10.1016/0022-328x(92)83187-m" @default.
• W2146384580 hasPublicationYear "1992" @default.
• W2146384580 type Work @default.
• W2146384580 sameAs 2146384580 @default.
• W2146384580 citedByCount "6" @default.
• W2146384580 countsByYear W21463845802014 @default.
• W2146384580 countsByYear W21463845802020 @default.
• W2146384580 crossrefType "journal-article" @default.
• W2146384580 hasAuthorship W2146384580A5016109186 @default.
• W2146384580 hasAuthorship W2146384580A5018178541 @default.
• W2146384580 hasAuthorship W2146384580A5052517822 @default.
• W2146384580 hasAuthorship W2146384580A5056951996 @default.
• W2146384580 hasAuthorship W2146384580A5084702465 @default.
• W2146384580 hasConcept C102931765 @default.
• W2146384580 hasConcept C116569031 @default.
• W2146384580 hasConcept C137955730 @default.
• W2146384580 hasConcept C145148216 @default.
• W2146384580 hasConcept C155647269 @default.
• W2146384580 hasConcept C161790260 @default.
• W2146384580 hasConcept C170493617 @default.
• W2146384580 hasConcept C178516000 @default.
• W2146384580 hasConcept C178790620 @default.
• W2146384580 hasConcept C185592680 @default.
• W2146384580 hasConcept C2182769 @default.
• W2146384580 hasConcept C2777954637 @default.
• W2146384580 hasConcept C2777961443 @default.
• W2146384580 hasConcept C2778597550 @default.
• W2146384580 hasConcept C2779782174 @default.
• W2146384580 hasConcept C504270822 @default.
• W2146384580 hasConcept C544153396 @default.
• W2146384580 hasConcept C55493867 @default.
• W2146384580 hasConcept C71240020 @default.
• W2146384580 hasConceptScore W2146384580C102931765 @default.
• W2146384580 hasConceptScore W2146384580C116569031 @default.
• W2146384580 hasConceptScore W2146384580C137955730 @default.
• W2146384580 hasConceptScore W2146384580C145148216 @default.
• W2146384580 hasConceptScore W2146384580C155647269 @default.
• W2146384580 hasConceptScore W2146384580C161790260 @default.
• W2146384580 hasConceptScore W2146384580C170493617 @default.
• W2146384580 hasConceptScore W2146384580C178516000 @default.
• W2146384580 hasConceptScore W2146384580C178790620 @default.
• W2146384580 hasConceptScore W2146384580C185592680 @default.
• W2146384580 hasConceptScore W2146384580C2182769 @default.
• W2146384580 hasConceptScore W2146384580C2777954637 @default.
• W2146384580 hasConceptScore W2146384580C2777961443 @default.
• W2146384580 hasConceptScore W2146384580C2778597550 @default.
• W2146384580 hasConceptScore W2146384580C2779782174 @default.
• W2146384580 hasConceptScore W2146384580C504270822 @default.
• W2146384580 hasConceptScore W2146384580C544153396 @default.
• W2146384580 hasConceptScore W2146384580C55493867 @default.
• W2146384580 hasConceptScore W2146384580C71240020 @default.
• W2146384580 hasIssue "3" @default.
• W2146384580 hasLocation W21463845801 @default.
• W2146384580 hasOpenAccess W2146384580 @default.

• next