Matches in SemOpenAlex for { <https://semopenalex.org/work/W2146543190> ?p ?o ?g. }
- W2146543190 endingPage "1753" @default.
- W2146543190 startingPage "1753" @default.
- W2146543190 abstract "A series of triarylamine-containing rhenium(I) diimine alkynyl complexes has been synthesized and some of their X-ray crystal structures have been determined. Low-energy transition bands at 402–444 nm were observed in the electronic absorption spectra and were tentatively assigned as an admixture of [dπ(Re) → π*(diimine)] metal-to-ligand charge-transfer (MLCT) and [π(CC−C6H4–R) → π* (diimine)] ligand-to-ligand charge-transfer (LLCT) transitions. They were found to give emission upon photo-excitation in the solid state and in fluid solution at room temperature and their emissive origins were assigned as derived predominantly from the triplet 3MLCT excited state, mixed with 3LLCT character as well as the 3IL state. Electrochemical studies revealed that the first oxidation process was mainly alkynyl ligand-based with mixing of the metal-centred contribution, whereas the first reduction was attributed to the ligand-centred reduction of the diimine ligand. Computational studies have been performed to provide further insight into the electrochemical and photophysical properties. The photochemical properties with triphenylamine were also studied by quenching experiments and time-resolved transient absorption spectroscopy. Some of these complexes were able to act as emitters in OLED devices and their electroluminescence (EL) behaviour was investigated." @default.
- W2146543190 created "2016-06-24" @default.
- W2146543190 creator A5012821084 @default.
- W2146543190 creator A5019852309 @default.
- W2146543190 creator A5038256949 @default.
- W2146543190 creator A5039925777 @default.
- W2146543190 creator A5060532769 @default.
- W2146543190 creator A5070777888 @default.
- W2146543190 creator A5074838420 @default.
- W2146543190 date "2013-01-01" @default.
- W2146543190 modified "2023-10-14" @default.
- W2146543190 title "Syntheses, photophysical, electroluminescence and computational studies of rhenium(i) diimine triarylamine-containing alkynyl complexes" @default.
- W2146543190 cites W1964837435 @default.
- W2146543190 cites W1967244854 @default.
- W2146543190 cites W1969096472 @default.
- W2146543190 cites W1970709482 @default.
- W2146543190 cites W1972206614 @default.
- W2146543190 cites W1976952039 @default.
- W2146543190 cites W1977316398 @default.
- W2146543190 cites W1981368803 @default.
- W2146543190 cites W1983885760 @default.
- W2146543190 cites W1985416572 @default.
- W2146543190 cites W1987502550 @default.
- W2146543190 cites W1989290803 @default.
- W2146543190 cites W1989899861 @default.
- W2146543190 cites W1990343645 @default.
- W2146543190 cites W1991975544 @default.
- W2146543190 cites W1995611172 @default.
- W2146543190 cites W1997516649 @default.
- W2146543190 cites W2002957942 @default.
- W2146543190 cites W2005391863 @default.
- W2146543190 cites W2006522238 @default.
- W2146543190 cites W2008423326 @default.
- W2146543190 cites W2014917029 @default.
- W2146543190 cites W2015723183 @default.
- W2146543190 cites W2018014235 @default.
- W2146543190 cites W2020004805 @default.
- W2146543190 cites W2026373027 @default.
- W2146543190 cites W2028629980 @default.
- W2146543190 cites W2028638351 @default.
- W2146543190 cites W2031392050 @default.
- W2146543190 cites W2033990154 @default.
- W2146543190 cites W2035166047 @default.
- W2146543190 cites W2039559098 @default.
- W2146543190 cites W2043621010 @default.
- W2146543190 cites W2043940281 @default.
- W2146543190 cites W2044560300 @default.
- W2146543190 cites W2045010824 @default.
- W2146543190 cites W2046412723 @default.
- W2146543190 cites W2047533017 @default.
- W2146543190 cites W2048400654 @default.
- W2146543190 cites W2053504597 @default.
- W2146543190 cites W2054527847 @default.
- W2146543190 cites W2055640795 @default.
- W2146543190 cites W2058848030 @default.
- W2146543190 cites W2061635910 @default.
- W2146543190 cites W2061772440 @default.
- W2146543190 cites W2063663126 @default.
- W2146543190 cites W2065838716 @default.
- W2146543190 cites W2068228867 @default.
- W2146543190 cites W2068532419 @default.
- W2146543190 cites W2069197437 @default.
- W2146543190 cites W2072049251 @default.
- W2146543190 cites W2077188122 @default.
- W2146543190 cites W2081325589 @default.
- W2146543190 cites W2083394102 @default.
- W2146543190 cites W2084169293 @default.
- W2146543190 cites W2089750496 @default.
- W2146543190 cites W2089781669 @default.
- W2146543190 cites W2089845615 @default.
- W2146543190 cites W2093770299 @default.
- W2146543190 cites W2094642658 @default.
- W2146543190 cites W2094827999 @default.
- W2146543190 cites W2101185742 @default.
- W2146543190 cites W2102386528 @default.
- W2146543190 cites W2105065645 @default.
- W2146543190 cites W2130910195 @default.
- W2146543190 cites W2142417414 @default.
- W2146543190 cites W2144821221 @default.
- W2146543190 cites W2144929089 @default.
- W2146543190 cites W2156208623 @default.
- W2146543190 cites W2166423006 @default.
- W2146543190 cites W2168121023 @default.
- W2146543190 cites W2171940615 @default.
- W2146543190 cites W2244695449 @default.
- W2146543190 cites W2325198840 @default.
- W2146543190 cites W2950719912 @default.
- W2146543190 cites W4254720078 @default.
- W2146543190 doi "https://doi.org/10.1039/c3nj00121k" @default.
- W2146543190 hasPublicationYear "2013" @default.
- W2146543190 type Work @default.
- W2146543190 sameAs 2146543190 @default.
- W2146543190 citedByCount "27" @default.
- W2146543190 countsByYear W21465431902013 @default.
- W2146543190 countsByYear W21465431902014 @default.
- W2146543190 countsByYear W21465431902015 @default.
- W2146543190 countsByYear W21465431902016 @default.
- W2146543190 countsByYear W21465431902017 @default.