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- W2146641185 abstract "The kinetics of ethane oxydehydrogenation to produce ethylene over AlPO-5, a member of the aluminophosphate molecular sieve family, has been investigated over the temperature range 748--798 K at atmospheric pressure. It was observed that parallel reactions to ethylene and carbon oxides occur on the surface. A kinetic model involving oxygen adsorption was proposed for the ethane oxydehydrogenation. On the basis of the kinetic analysis, it is suggested that the reactions of ethane on the surface through two different sites are the rate-determining step. The apparent activation energy was 83 kcal/mol. For oxygen adsorption on the surface, the changes of enthalpy and entropy were {minus}23 kcal/mol and {minus}25 cal/mol K, respectively. These explain the adsorption phenomena reasonably." @default.
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- W2146641185 date "1993-12-01" @default.
- W2146641185 modified "2023-09-27" @default.
- W2146641185 title "Kinetic study of ethane oxydehydrogenation over AlPO-5" @default.
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- W2146641185 doi "https://doi.org/10.1021/ie00024a005" @default.
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