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- W2146692019 abstract "Well graphitized carbon nano-onions (CNOs) with large yield have been synthesized by the catalytic decomposition of methane over an unsupported Ni–Fe catalyst at 850 °C. The unsupported Ni–Fe catalyst was prepared by a reduction-substitution method. In the Ni–Fe alloy particle, α-Fe(Ni) phase (kamacite) transforms to γ-Fe–Ni phase at the high temperature for hydrogen reduction and chemical vapor deposition. The synthesized CNOs contain either a Fe0.64Ni0.36 particle or a hollow core with thick graphitic layers and a polyhedral shape. Based on the characterization, we believe that the catalyst involved in the synthesis of carbon products is Fe–Ni–C austenite rather than the γ-Fe–Ni phase (Fe0.64Ni0.36). A growth mechanism for the CNOs is proposed." @default.
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- W2146692019 date "2011-04-01" @default.
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- W2146692019 title "The efficient synthesis of carbon nano-onions using chemical vapor deposition on an unsupported Ni–Fe alloy catalyst" @default.
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- W2146692019 doi "https://doi.org/10.1016/j.carbon.2010.11.030" @default.
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