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- W2146933759 abstract "Redox copolymerization of N-vinyl-2-pyrrolidone (NVP) with methyl methacrylate (MMA) was carried out using titanium(III)-- dimethylglyoxime [Ti(III)-DMG] redox initiator in aqueous sulfuric acid-alcohol media. The resulting copolymer was characterized by FTIR, 1H-NMR, and 13C-NMR spectroscopic methods and elemental analysis. Thermal properties of the copolymer were determined by differential scanning calorimetric technique and thermogravimetric analysis. The reactivity ratios of the monomers were computed by Fineman-Ross, Kelen-Tudos, and extended Kelen-Tudos methods at lower conversion. The reactivity ratios obtained r1 (MMA) 1.69 and r2 (NVP) 0.03 showed richer content of MMA than NVP in the copolymer having extreme ideal behavior. The distribution of monomer sequence along the copolymer chain was calculated using a statistical method based on reactivity ratios. Ti(III)-DMG redox initiator showed increased addition of NVP to MMA during copolymerization." @default.
- W2146933759 created "2016-06-24" @default.
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- W2146933759 date "2013-01-01" @default.
- W2146933759 modified "2023-10-18" @default.
- W2146933759 title "Possibilities for reducing tractor engine friction losses at cold start using an ultrasonic irradiation technique" @default.
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- W2146933759 doi "https://doi.org/10.3906/tar-1203-75" @default.
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