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• W2146990593 abstract "The solubility of water in the hydrophobic 1-alkyl-3-methylimidazolium hexafluorophosphate (alkyl = butyl, hexyl, and octyl) ionic liquids, can be significantly increased in the presence of ethanol as a co-solute. 1-Hexyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate are completely miscible with ethanol, and immiscible with water, whereas 1-butyl-3-methylimidazolium hexafluorophosphate is totally miscible with aqueous ethanol only between 0.5–0.9 mole fraction ethanol at 25 °C. At higher and lower mole fraction of ethanol, the aqueous and IL components are only partially miscible and a biphasic system is obtained upon mixing equal volumes of the IL and aqueous ethanol. The observation of a large range of total miscibility between water and the IL in the three-component system has important implications for purifications and separations from IL." @default.
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• W2146990593 date "2001-12-14" @default.
• W2146990593 modified "2023-10-14" @default.
• W2146990593 title "On the solubilization of water with ethanol in hydrophobic hexafluorophosphate ionic liquids" @default.
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• W2146990593 doi "https://doi.org/10.1039/b108905f" @default.
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