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- W2147141808 endingPage "2528" @default.
- W2147141808 startingPage "2486" @default.
- W2147141808 abstract "Asymmetric catalysis with transition-metal complexes is the basis for a vast array of stereoselective transformations and has changed the face of modern synthetic chemistry. Key to this success has been the design of chiral ligands to control the regio-, diastereo-, and enantioselectivity. Phosphoramidites have emerged as a highly versatile and readily accessible class of chiral ligands. Their modular structure enables the formation of ligand libraries and easy fine-tuning for a specific catalytic reaction. Phosphoramidites frequently show exceptional levels of stereocontrol, and their monodentate nature is essential in combinatorial catalysis, where a ligand-mixture approach is used. In this Review, recent developments in asymmetric catalysis with phosphoramidites used as ligands are discussed, with a focus on the formation of carbon–carbon and carbon–heteroatom bonds." @default.
- W2147141808 created "2016-06-24" @default.
- W2147141808 creator A5061028750 @default.
- W2147141808 creator A5087713906 @default.
- W2147141808 date "2010-03-29" @default.
- W2147141808 modified "2023-10-13" @default.
- W2147141808 title "Phosphoramidites: Privileged Ligands in Asymmetric Catalysis" @default.
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