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- W2147145448 abstract "A conceptually new approach affords optically active α-fluoroketones 3 in high yields with up to 99 % ee from racemic α-fluoro-β-ketoesters 1 in the presence of a chiral phosphinooxazoline ligand 2. The palladium-catalyzed decarboxylation/allylation reaction also allows the highly enantioselective construction of an all-carbon quaternary center. dba=dibenzylideneacetone." @default.
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- W2147145448 date "2005-11-08" @default.
- W2147145448 modified "2023-10-18" @default.
- W2147145448 title "Synthesis of Chiral α‐Fluoroketones through Catalytic Enantioselective Decarboxylation" @default.
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- W2147145448 doi "https://doi.org/10.1002/anie.200502703" @default.
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