Matches in SemOpenAlex for { <https://semopenalex.org/work/W2147173888> ?p ?o ?g. }
- W2147173888 endingPage "6477" @default.
- W2147173888 startingPage "6470" @default.
- W2147173888 abstract "The electropolymerization of thioaniline-modified Au nanoparticles (NPs) on thioaniline monolayer-functionalized electrodes in the presence of Zn(II)-protoporphyrin IX yields bis aniline-crosslinked Au NPs matrices that include molecular imprinted sites for binding the Zn(II)-protoporphyrin IX photosensitizer. The binding of the photosensitizer yields photoelectrochemically active electrodes that produce anodic photocurrents in the presence of the electron donor benzohydroquinone. The efficient photocurrents formed in the presence of the imprinted electrode are attributed to the high-affinity binding of the photosensitizer to the imprinted sites, Ka = 3.2 × 106 m−1, and to the effective transport of the photoejected electrons to the bulk electrode via the bridged Au NPs matrix. Similarly, a N,N′-dialkyl-4,4′-bipyridinium-modified Zn(II)-protoporphyrin IX photosensitizer-electron acceptor dyad is imprinted in the bis aniline-crosslinked Au NPs matrix. The photocurrent generated by the imprinted matrix is approximately twofold higher as compared to the photocurrent generated by the Zn(II)-protoporphyrin IX-imprinted Au NPs matrix. The efficient photocurrents generated in the presence of the bipyridinium-modified Zn(II)-protoporphyrin IX-imprinted matrix are attributed to the effective primary charge separation of the electron–hole species in the dyad structure, followed by the effective transport of the photoejected electrons to the electrode via the bis aniline-crosslinked Au NPs matrix." @default.
- W2147173888 created "2016-06-24" @default.
- W2147173888 creator A5037842873 @default.
- W2147173888 creator A5054929012 @default.
- W2147173888 creator A5074665028 @default.
- W2147173888 creator A5089144929 @default.
- W2147173888 date "2015-09-24" @default.
- W2147173888 modified "2023-10-16" @default.
- W2147173888 title "Zn(II)-Protoporphyrin IX-Based Photosensitizer-Imprinted Au-Nanoparticle-Modified Electrodes for Photoelectrochemical Applications" @default.
- W2147173888 cites W1836476934 @default.
- W2147173888 cites W1899490227 @default.
- W2147173888 cites W1963479887 @default.
- W2147173888 cites W1965391808 @default.
- W2147173888 cites W1965657790 @default.
- W2147173888 cites W1970121975 @default.
- W2147173888 cites W1972195348 @default.
- W2147173888 cites W1972241205 @default.
- W2147173888 cites W1973370020 @default.
- W2147173888 cites W1974213493 @default.
- W2147173888 cites W1977600584 @default.
- W2147173888 cites W1985620110 @default.
- W2147173888 cites W1990189209 @default.
- W2147173888 cites W1990755839 @default.
- W2147173888 cites W1992679438 @default.
- W2147173888 cites W1996801798 @default.
- W2147173888 cites W1996829882 @default.
- W2147173888 cites W2000706992 @default.
- W2147173888 cites W2004880801 @default.
- W2147173888 cites W2005743369 @default.
- W2147173888 cites W2014876663 @default.
- W2147173888 cites W2016088184 @default.
- W2147173888 cites W2021906850 @default.
- W2147173888 cites W2024700582 @default.
- W2147173888 cites W2028583031 @default.
- W2147173888 cites W2030612027 @default.
- W2147173888 cites W2035283400 @default.
- W2147173888 cites W2037653040 @default.
- W2147173888 cites W2040660664 @default.
- W2147173888 cites W2042131251 @default.
- W2147173888 cites W2043447627 @default.
- W2147173888 cites W2043645287 @default.
- W2147173888 cites W2044106917 @default.
- W2147173888 cites W2046049711 @default.
- W2147173888 cites W2047603692 @default.
- W2147173888 cites W2051219661 @default.
- W2147173888 cites W2053133246 @default.
- W2147173888 cites W2055069556 @default.
- W2147173888 cites W2058319198 @default.
- W2147173888 cites W2059009076 @default.
- W2147173888 cites W2059546938 @default.
- W2147173888 cites W2062127424 @default.
- W2147173888 cites W2064046972 @default.
- W2147173888 cites W2073034707 @default.
- W2147173888 cites W2073777485 @default.
- W2147173888 cites W2082705520 @default.
- W2147173888 cites W2086361014 @default.
- W2147173888 cites W2088674397 @default.
- W2147173888 cites W2093727176 @default.
- W2147173888 cites W2099861285 @default.
- W2147173888 cites W2100110662 @default.
- W2147173888 cites W2102110614 @default.
- W2147173888 cites W2104871327 @default.
- W2147173888 cites W2106797497 @default.
- W2147173888 cites W2111243987 @default.
- W2147173888 cites W2112496058 @default.
- W2147173888 cites W2113249009 @default.
- W2147173888 cites W2116327492 @default.
- W2147173888 cites W2119536455 @default.
- W2147173888 cites W2132799109 @default.
- W2147173888 cites W2134035658 @default.
- W2147173888 cites W2134823940 @default.
- W2147173888 cites W2134890691 @default.
- W2147173888 cites W2136545558 @default.
- W2147173888 cites W2138935600 @default.
- W2147173888 cites W2141503847 @default.
- W2147173888 cites W2150447974 @default.
- W2147173888 cites W2156164338 @default.
- W2147173888 cites W2157919252 @default.
- W2147173888 cites W2162001660 @default.
- W2147173888 cites W2164201018 @default.
- W2147173888 cites W2168063349 @default.
- W2147173888 cites W2168415885 @default.
- W2147173888 cites W2169498876 @default.
- W2147173888 cites W2170416259 @default.
- W2147173888 cites W2312965412 @default.
- W2147173888 cites W2314021691 @default.
- W2147173888 cites W2316971231 @default.
- W2147173888 cites W2322790099 @default.
- W2147173888 cites W2324917694 @default.
- W2147173888 cites W2327103201 @default.
- W2147173888 cites W2333447692 @default.
- W2147173888 cites W2334637553 @default.
- W2147173888 cites W2335506970 @default.
- W2147173888 cites W3005267976 @default.
- W2147173888 cites W3023438842 @default.
- W2147173888 cites W4235767130 @default.
- W2147173888 cites W4239137214 @default.
- W2147173888 cites W4242011368 @default.