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- W2147263967 abstract "Two new coordination polymers [Cd(tdc)(bpy)(H2O)]n (1) and [Cd(tdc)(phen)]n (2) (H2tdc = thiophene-2,5-dicarboxylic acid, bpy = 2,2′-bipyridine and phen = 1,10-phenanthroline) have been synthesized under hydrothermal condition. Their crystal structures have been established by X-ray single-crystal diffraction. Complex 1 crystallizes in the orthorhombic space group Fdd2 with a = 14.757(7), b = 45.38(2), c = 10.518(5) Å, V = 7044(6) Å3, Z = 16; 2 in the monoclinic space group P21/c with a = 7.262(1), b = 21.970(2), c = 10.051(1) Å, β = 105.01(1)°, V = 1548.8(2) Å3, Z = 4. Both of them are double-stranded chains and further assembled into three-dimensional networks by π-π stacking interactions. 1 and 2 are stable in air, and show blue photoluminescence at 415 nm and 410 nm, respectively." @default.
- W2147263967 created "2016-06-24" @default.
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- W2147263967 date "2005-04-01" @default.
- W2147263967 modified "2023-10-12" @default.
- W2147263967 title "Syntheses and Crystal Structures of Cadmium Complexes with Thiophenedicarboxylate and Bipyridine-like Ligands" @default.
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- W2147263967 doi "https://doi.org/10.1002/zaac.200400461" @default.
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