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- W2147454612 abstract "An der Biosynthese des tetracyclischen Peptidantibiotikums Epidermin ist das Enzym EpiD beteiligt; es setzt Peptidyl-Cysteine zu Thioenolen um [Gl. (a)]. Die Thioenole sind instabil und zersetzen sich innerhalb von Stunden. Die oxidative Decarboxylierung eines 13C-markierten Peptidsubstrats wurde massenspektrometrisch und NMR-spektroskopisch verfolgt. Dadurch konnte die Struktur der Biosynthesezwischenstufe bewiesen werden. R = Peptidylrest." @default.
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- W2147454612 date "1996-09-20" @default.
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- W2147454612 title "Thioenole aus Peptidyl-Cysteinen: oxidative Decarboxylierung eines13C-markierten Substrats" @default.
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- W2147454612 doi "https://doi.org/10.1002/ange.19961081811" @default.
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