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- W2147493095 abstract "A regiospecific and high diastereoselective synthesis of trans-glycidic amides coming from a common pseudoephedrine sulfonium salt 2 precursor is presented. This is the first example in where the diastereoselectivity is controlled by a chiral noncyclic amide fragment. The epoxidation reaction provides alkyl or aryl glycidic amides in good to excellent yields and exclusive trans selectivity. Finally, through of a chemospecific 6-exo-tet ring closure of trans-epoxyamides we access to morpholin-3-ones densely functionalized with excellent chemical and stereochemical yields." @default.
- W2147493095 created "2016-06-24" @default.
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- W2147493095 date "2012-12-01" @default.
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- W2147493095 title "Diastereoselective synthesis of aryl and alkyl trans-glycidic amides from pseudoephedrine-derived sulfonium salt. Chemospecific exo-tet ring closure for morpholin-3-ones" @default.
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- W2147493095 doi "https://doi.org/10.1016/j.tet.2012.09.047" @default.
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