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• W2147589624 abstract "The chemist is accustomed to deriving structures and preferred conformations of organic compounds from rigid molecular models and standard values for bond lengths, bond angles, and torsional profiles. In the case of strained compounds, this rigid structural model has to be abandoned and replaced by a flexible one which takes individual conditions of strain into consideration. It is shown, on the basis of new experimental structure data, that the force field method is suitable and highly reliable for the calculation of structural parameters and preferred conformations of strained compounds. It is, therefore, capable of replacing the rigid molecular model. Furthermore, the systematic analysis of strain induced angle and bond deformation gives a new pivot for the development of a qualitative discussion of deformation in strained molecules and hence for improved conformational analysis. — In the course of this work we were able to isolate two rotamers of D,L-3,4-di(1-adamantyl)-2,2,5,5-tetramethylhexane; this is the first isolation of a rotamer pair of an aliphatic hydrocarbon." @default.
• W2147589624 created "2016-06-24" @default.
• W2147589624 creator A5004402364 @default.
• W2147589624 creator A5086009396 @default.
• W2147589624 date "1985-06-01" @default.
• W2147589624 modified "2023-09-23" @default.
• W2147589624 title "Consequences of Strain for the Structure of Aliphatic Molecules" @default.
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• W2147589624 doi "https://doi.org/10.1002/anie.198505293" @default.
• W2147589624 hasPublicationYear "1985" @default.
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