FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2147611074> ?p ?o ?g. }

• W2147611074 endingPage "1897" @default.
• W2147611074 startingPage "1891" @default.
• W2147611074 abstract "The photodissociation of formic acid has been studied experimentally and theoretically. Ab initio calculations were performed to study the dissociative profiles of five reaction channels on the S0, S1, and T1 potential energy surfaces. The vibrationally excited nascent products were detected using a time-resolved Fourier transform infrared spectrometer after laser photolysis at 248 or 193 nm. In the 248 nm photolysis, the HCOOH molecule was first excited to the S1 state, but it was found that the dissociation takes place on the S0 surface after internal conversion. The products of the vibrationally excited CO, CO2(v3) and H2O(v1) were detected. During the dissociation process the vibrationally energized molecule is geometrically memorized and dynamically controlled, with the yield preference of CO and H2O over that of CO2 and H2. The ratio of CO(v⩾1)/CO2(v⩾1) is estimated as &lt;7.5. Vibrationally excited CO (v) and CO2(v3) are also found in the 193 nm photolysis but the CO/CO2 ratio increases to 11. Most of the dissociation is thought to occur on the S0 state. At this wavelength another dissociation channel which produces OH and HCO radicals on S1 surface has been identified. The dissociation is unlikely to occur on the T1 surface, as the energy barriers are fairly high." @default.
• W2147611074 created "2016-06-24" @default.
• W2147611074 creator A5014751069 @default.
• W2147611074 creator A5045230594 @default.
• W2147611074 creator A5069843494 @default.
• W2147611074 creator A5083387300 @default.
• W2147611074 creator A5087674282 @default.
• W2147611074 date "2000-08-01" @default.
• W2147611074 modified "2023-10-12" @default.
• W2147611074 title "Photodissociation of formic acid" @default.
• W2147611074 cites W127929529 @default.
• W2147611074 cites W1529454005 @default.
• W2147611074 cites W1967023734 @default.
• W2147611074 cites W1982690998 @default.
• W2147611074 cites W1991053055 @default.
• W2147611074 cites W1996959317 @default.
• W2147611074 cites W1998557478 @default.
• W2147611074 cites W2012157756 @default.
• W2147611074 cites W2015739097 @default.
• W2147611074 cites W2039638231 @default.
• W2147611074 cites W2041073532 @default.
• W2147611074 cites W2041969159 @default.
• W2147611074 cites W2043561661 @default.
• W2147611074 cites W2048489687 @default.
• W2147611074 cites W2057446220 @default.
• W2147611074 cites W2058068591 @default.
• W2147611074 cites W2065683666 @default.
• W2147611074 cites W2069006374 @default.
• W2147611074 cites W2075611717 @default.
• W2147611074 cites W2099246826 @default.
• W2147611074 cites W2399473178 @default.
• W2147611074 cites W43255328 @default.
• W2147611074 cites W84560044 @default.
• W2147611074 doi "https://doi.org/10.1063/1.482076" @default.
• W2147611074 hasPublicationYear "2000" @default.
• W2147611074 type Work @default.
• W2147611074 sameAs 2147611074 @default.
• W2147611074 citedByCount "62" @default.
• W2147611074 countsByYear W21476110742012 @default.
• W2147611074 countsByYear W21476110742014 @default.
• W2147611074 countsByYear W21476110742015 @default.
• W2147611074 countsByYear W21476110742016 @default.
• W2147611074 countsByYear W21476110742017 @default.
• W2147611074 countsByYear W21476110742018 @default.
• W2147611074 countsByYear W21476110742019 @default.
• W2147611074 countsByYear W21476110742020 @default.
• W2147611074 countsByYear W21476110742021 @default.
• W2147611074 countsByYear W21476110742022 @default.
• W2147611074 countsByYear W21476110742023 @default.
• W2147611074 crossrefType "journal-article" @default.
• W2147611074 hasAuthorship W2147611074A5014751069 @default.
• W2147611074 hasAuthorship W2147611074A5045230594 @default.
• W2147611074 hasAuthorship W2147611074A5069843494 @default.
• W2147611074 hasAuthorship W2147611074A5083387300 @default.
• W2147611074 hasAuthorship W2147611074A5087674282 @default.
• W2147611074 hasConcept C102931765 @default.
• W2147611074 hasConcept C121332964 @default.
• W2147611074 hasConcept C139066938 @default.
• W2147611074 hasConcept C147789679 @default.
• W2147611074 hasConcept C178790620 @default.
• W2147611074 hasConcept C181500209 @default.
• W2147611074 hasConcept C184779094 @default.
• W2147611074 hasConcept C185592680 @default.
• W2147611074 hasConcept C2777379063 @default.
• W2147611074 hasConcept C32909587 @default.
• W2147611074 hasConcept C43617362 @default.
• W2147611074 hasConcept C54582936 @default.
• W2147611074 hasConcept C75473681 @default.
• W2147611074 hasConceptScore W2147611074C102931765 @default.
• W2147611074 hasConceptScore W2147611074C121332964 @default.
• W2147611074 hasConceptScore W2147611074C139066938 @default.
• W2147611074 hasConceptScore W2147611074C147789679 @default.
• W2147611074 hasConceptScore W2147611074C178790620 @default.
• W2147611074 hasConceptScore W2147611074C181500209 @default.
• W2147611074 hasConceptScore W2147611074C184779094 @default.
• W2147611074 hasConceptScore W2147611074C185592680 @default.
• W2147611074 hasConceptScore W2147611074C2777379063 @default.
• W2147611074 hasConceptScore W2147611074C32909587 @default.
• W2147611074 hasConceptScore W2147611074C43617362 @default.
• W2147611074 hasConceptScore W2147611074C54582936 @default.
• W2147611074 hasConceptScore W2147611074C75473681 @default.
• W2147611074 hasIssue "5" @default.
• W2147611074 hasLocation W21476110741 @default.
• W2147611074 hasOpenAccess W2147611074 @default.
• W2147611074 hasPrimaryLocation W21476110741 @default.
• W2147611074 hasRelatedWork W1637838377 @default.
• W2147611074 hasRelatedWork W1975504879 @default.
• W2147611074 hasRelatedWork W1985471966 @default.
• W2147611074 hasRelatedWork W2035283393 @default.
• W2147611074 hasRelatedWork W2038890347 @default.
• W2147611074 hasRelatedWork W2042439856 @default.
• W2147611074 hasRelatedWork W2077248982 @default.
• W2147611074 hasRelatedWork W2146211863 @default.
• W2147611074 hasRelatedWork W2161274829 @default.
• W2147611074 hasRelatedWork W2185389097 @default.
• W2147611074 hasVolume "113" @default.
• W2147611074 isParatext "false" @default.
• W2147611074 isRetracted "false" @default.

• next