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- W2147669775 abstract "Abstract The synthesis and characterization of two new cobalt(III) complexes of corrole: [triphenylphosphine- (2,3,7,8,12,13,17,18-octamethyl-10-phenylcorrolato)cobalt(III)] and [triphenylphosphine(2,3,7,8,12,13,17,18-octamethyl- 5,10,15-triphenylcorrolato)cobalt(III) are reported. Such complexes represent the first examples of meso - substituted corrolates reported in the literature. The insertion of one or three phenyl groups at the meso -positions of the macrocyclic ligand has been achieved by designing different synthetic strategies. The spectroscopic characterization of the complexes shows the peculiarity of the corrole ligand which maintains a planar structure despite the steric hindrance of the peripheral substituents." @default.
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- W2147669775 date "1993-01-01" @default.
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- W2147669775 title "Synthesis and characterization of cobalt(III) complexes of meso-phenyl-substituted corroles" @default.
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- W2147669775 doi "https://doi.org/10.1016/s0020-1693(00)82913-8" @default.
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