FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2147716098> ?p ?o ?g. }

• W2147716098 endingPage "1882" @default.
• W2147716098 startingPage "1873" @default.
• W2147716098 abstract "Abstract Current research in materials has devoted much attention to graphene, with a considerable amount of the chemical manipulation going through the oxidized state of the material, known as graphene oxide (GO). In this report, the hydroxyl functionalities in GO, the vast majority that must be allylic alcohols, are subjected to Johnson−Claisen rearrangement conditions. In these conditions, a [3, 3] sigmatropic rearrangement after reaction with triethyl orthoacetate gives rise to an ester functional group, attached to the graphitic framework via a robust C−C bond. This variation of the Claisen rearrangement offers an unprecedented versatility of further functionalizations, while maintaining the desirable properties of unfunctionalized graphene. The resultant functional groups were found to withstand reductive treatments for the deoxygenation of graphene sheets and a resumption of electronic conductivity is observed. The ester groups are easily saponified to carboxylic acids in situ with basic conditions, to give water‐soluble graphene. The ester functionality can be further reacted as is, or the carboxylic acid can easily be converted to the more reactive acid chloride. Subsequent amide formation yields up to 1 amide in 15 graphene carbons and increases intergallery spacing up to 12.8 Å, suggesting utility of this material in capacitors and in gas storage. Other functionalization schemes, which include the installation of terminal alkynes and dipolar cycloadditions, allow for the synthesis of a highly positively charged, water‐soluble graphene. The highly negatively and positively charged graphenes (zeta potentials of −75 mV and +56 mV, respectively), are successfully used to build layer‐by‐layer (LBL) constructs." @default.
• W2147716098 created "2016-06-24" @default.
• W2147716098 creator A5004974178 @default.
• W2147716098 creator A5045135784 @default.
• W2147716098 date "2012-11-06" @default.
• W2147716098 modified "2023-10-17" @default.
• W2147716098 title "Functional Graphenic Materials Via a Johnson−Claisen Rearrangement" @default.
• W2147716098 cites W1965460216 @default.
• W2147716098 cites W1967387244 @default.
• W2147716098 cites W1969695518 @default.
• W2147716098 cites W1970897023 @default.
• W2147716098 cites W1977980322 @default.
• W2147716098 cites W1978122890 @default.
• W2147716098 cites W1993008721 @default.
• W2147716098 cites W1994387220 @default.
• W2147716098 cites W1996521710 @default.
• W2147716098 cites W2001642272 @default.
• W2147716098 cites W2014585972 @default.
• W2147716098 cites W2018809718 @default.
• W2147716098 cites W2021650639 @default.
• W2147716098 cites W2029474094 @default.
• W2147716098 cites W2033962521 @default.
• W2147716098 cites W2043927293 @default.
• W2147716098 cites W2065062234 @default.
• W2147716098 cites W2076301381 @default.
• W2147716098 cites W2078792724 @default.
• W2147716098 cites W2101312334 @default.
• W2147716098 cites W2109375754 @default.
• W2147716098 cites W2109807803 @default.
• W2147716098 cites W2113228695 @default.
• W2147716098 cites W2116730433 @default.
• W2147716098 cites W2132384935 @default.
• W2147716098 cites W2135479172 @default.
• W2147716098 cites W2138112440 @default.
• W2147716098 cites W2148465347 @default.
• W2147716098 cites W2152685429 @default.
• W2147716098 cites W2154678311 @default.
• W2147716098 cites W2312850474 @default.
• W2147716098 cites W2335265092 @default.
• W2147716098 cites W2952197875 @default.
• W2147716098 cites W4233194460 @default.
• W2147716098 cites W4256503849 @default.
• W2147716098 doi "https://doi.org/10.1002/adfm.201201954" @default.
• W2147716098 hasPublicationYear "2012" @default.
• W2147716098 type Work @default.
• W2147716098 sameAs 2147716098 @default.
• W2147716098 citedByCount "59" @default.
• W2147716098 countsByYear W21477160982013 @default.
• W2147716098 countsByYear W21477160982014 @default.
• W2147716098 countsByYear W21477160982015 @default.
• W2147716098 countsByYear W21477160982016 @default.
• W2147716098 countsByYear W21477160982017 @default.
• W2147716098 countsByYear W21477160982018 @default.
• W2147716098 countsByYear W21477160982019 @default.
• W2147716098 countsByYear W21477160982020 @default.
• W2147716098 countsByYear W21477160982021 @default.
• W2147716098 countsByYear W21477160982022 @default.
• W2147716098 countsByYear W21477160982023 @default.
• W2147716098 crossrefType "journal-article" @default.
• W2147716098 hasAuthorship W2147716098A5004974178 @default.
• W2147716098 hasAuthorship W2147716098A5045135784 @default.
• W2147716098 hasBestOaLocation W21477160982 @default.
• W2147716098 hasConcept C120095180 @default.
• W2147716098 hasConcept C155672457 @default.
• W2147716098 hasConcept C159985019 @default.
• W2147716098 hasConcept C161790260 @default.
• W2147716098 hasConcept C171250308 @default.
• W2147716098 hasConcept C178790620 @default.
• W2147716098 hasConcept C185592680 @default.
• W2147716098 hasConcept C188027245 @default.
• W2147716098 hasConcept C192562407 @default.
• W2147716098 hasConcept C2777332933 @default.
• W2147716098 hasConcept C2778439535 @default.
• W2147716098 hasConcept C2779074116 @default.
• W2147716098 hasConcept C2779778602 @default.
• W2147716098 hasConcept C2779851234 @default.
• W2147716098 hasConcept C2780567667 @default.
• W2147716098 hasConcept C30080830 @default.
• W2147716098 hasConcept C521977710 @default.
• W2147716098 hasConcept C86181022 @default.
• W2147716098 hasConceptScore W2147716098C120095180 @default.
• W2147716098 hasConceptScore W2147716098C155672457 @default.
• W2147716098 hasConceptScore W2147716098C159985019 @default.
• W2147716098 hasConceptScore W2147716098C161790260 @default.
• W2147716098 hasConceptScore W2147716098C171250308 @default.
• W2147716098 hasConceptScore W2147716098C178790620 @default.
• W2147716098 hasConceptScore W2147716098C185592680 @default.
• W2147716098 hasConceptScore W2147716098C188027245 @default.
• W2147716098 hasConceptScore W2147716098C192562407 @default.
• W2147716098 hasConceptScore W2147716098C2777332933 @default.
• W2147716098 hasConceptScore W2147716098C2778439535 @default.
• W2147716098 hasConceptScore W2147716098C2779074116 @default.
• W2147716098 hasConceptScore W2147716098C2779778602 @default.
• W2147716098 hasConceptScore W2147716098C2779851234 @default.
• W2147716098 hasConceptScore W2147716098C2780567667 @default.
• W2147716098 hasConceptScore W2147716098C30080830 @default.
• W2147716098 hasConceptScore W2147716098C521977710 @default.
• W2147716098 hasConceptScore W2147716098C86181022 @default.

• next