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- W2147907966 abstract "Abstract 5‐Alkyl‐ and 5‐alkenylresorcinols, as well as their hydroxylated derivatives, were extracted from mango ( Mangifera indica L.) peels, purified on polyamide and characterized by high‐performance liquid chromatography/atmospheric pressure chemical ionization mass spectrometry (HPLC/APcI‐MS) for the first time. Among the 15 compounds analyzed, 3 major and 12 minor C 15 ‐, C 17 ‐, and C 19 ‐substituted resorcinols and related analogues, showing varying degrees of unsaturation, were characterized by their specific fragmentation patterns in collision‐induced dissociation experiments. This marks the first report on the occurrence of mono‐, di‐, and triunsaturated C 15 ‐homologues, saturated and triunsaturated C 17 ‐homologues, and mono‐ and diunsaturated C 19 ‐homologues in mango peels. Additionally, several hydroxylated C 15 ‐ and C 17 ‐homologues, also not yet described in mango, and a C 14 ‐monoene, unique because of its even‐numbered side chain, were tentatively identified on the basis of their fragmentation patterns. The results obtained in the present study indicate that HPLC‐DAD‐APcI‐MS n , combined with the newly developed solid‐phase extraction, is a powerful tool for the analysis of alk(en)ylresorcinols and could therefore be used for their determination in various matrices. Copyright © 2007 John Wiley & Sons, Ltd." @default.
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- W2147907966 date "2007-02-13" @default.
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- W2147907966 title "Characterization of major and minor alk(en)ylresorcinols from mango (Mangifera indica L.) peels by high-performance liquid chromatography/atmospheric pressure chemical ionization mass spectrometry" @default.
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- W2147907966 doi "https://doi.org/10.1002/rcm.2919" @default.
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