Matches in SemOpenAlex for { <https://semopenalex.org/work/W2148032221> ?p ?o ?g. }
- W2148032221 abstract "[3264-82-2] C10H14NiO4 (MW 256.93) InChI = 1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; InChIKey = BMGNSKKZFQMGDH-FDGPNNRMSA-L (catalyst for oligomerization, telomerization, hydrosilylation, hydrogenation, reduction, cross-coupling, oxidation, conjugate addition, addition to multiple bonds, and rearrangements1) Alternate Name: bis(acetylacetonato)nickel(II). Physical Data: pale green solid, mp 240 °C (dec); see also 2,4‐Pentanedione. Solubility: sol ethers and aromatic and halogenated hydrocarbons. Analysis of Reagent Purity: atomic absorption is the method most commonly used. Preparative Methods: commercially available; can be prepared from Nickel(II) Chloride.1d Purification: recrystallize from benzene and sublime under vacuum (10−3 mmHg).1c Handling, Storage, and Precautions: nickel is now recognized as a cancer suspect agent as well as a possible teratogen and due precautions should be taken when handling the reagent. The anhydrous solid is stable, but is an irritant and hygroscopic and should preferably be stored in a sealed container to preclude contact with air and moisture. Solutions are more susceptible to atmospheric oxidation." @default.
- W2148032221 created "2016-06-24" @default.
- W2148032221 creator A5053884602 @default.
- W2148032221 date "2001-04-15" @default.
- W2148032221 modified "2023-10-18" @default.
- W2148032221 title "Nickel(II) Acetylacetonate" @default.
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- W2148032221 doi "https://doi.org/10.1002/047084289x.rn006" @default.
- W2148032221 hasPublicationYear "2001" @default.
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