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• W2148087137 abstract "Abstract A novel matrix‐assisted laser desorption/ionisation quadrupole ion trap time‐of‐flight (MALDI QIT ToF) mass spectrometer has been used to analyse high mass peptide ions exceeding 2000 Da. Human adrenocorticotropic hormone (fragment 18–39) and oxidised bovine insulin chain B were utilised to evaluate the performance of the instrument both in MS and in MS/MS mode. Its ability to efficiently isolate ions and to fragment them using collisionally activated decomposition (CAD) has been demonstrated using mixtures diluted to the low‐femtomole level on target. Additionally, multiple stage mass spectrometry (MS/MS/MS) provides a second‐generation product ion spectrum in which new fragment ions are detected and new stretches of amino acids are identified. Copyright © 2003 John Wiley & Sons, Ltd." @default.
• W2148087137 created "2016-06-24" @default.
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• W2148087137 date "2003-05-14" @default.
• W2148087137 modified "2023-10-14" @default.
• W2148087137 title "Analysis of high mass peptides using a novel matrix‐assisted laser desorption/ionisation quadrupole ion trap time‐of‐flight mass spectrometer" @default.
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• W2148087137 doi "https://doi.org/10.1002/rcm.1044" @default.
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