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- W2148114010 abstract "The synthesis of diethyl β-aminovinylphosphonates 2 from acetoxy phosphonate 1 is described. The reaction entails an organocatalyzed substitution of the acetoxy group by primary or secondary amines. The use of a catalytic amount of DABCO is necessary if the amine is not nucleophilic enough, otherwise a strong nucleophilic amine can react without organocatalyst. The reaction led to a series of functionalized title compounds in good to excellent yields." @default.
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- W2148114010 date "2010-07-01" @default.
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- W2148114010 title "Synthesis of β-aminovinylphosphonates by organocatalytic nucleophilic displacement of acetate with amines" @default.
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- W2148114010 doi "https://doi.org/10.1016/j.tetlet.2010.05.050" @default.
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