Matches in SemOpenAlex for { <https://semopenalex.org/work/W2148270717> ?p ?o ?g. }
- W2148270717 endingPage "136" @default.
- W2148270717 startingPage "129" @default.
- W2148270717 abstract "The benzophenone dianion [diphenyloxidomethanide, (Ph2CO)2−], which occurs in the well known deeply violet sodium/benzophenone tetrahydrofuran solutions, was crystallised with sodium cations in form of the two polymeric chain compounds [Na2(Ph2CO)(tetraglyme)]∞1 and [Na2(Ph2CO)(thf)2]∞2. It was found to aggregate with its conjugated acid, the alcoholate (Ph2CHO)−, around a central unit of sodium hydroxide, resulting in the mixed cage compound [Na13(Ph2CO)4(Ph2CHO)4(OH)(mtbe)4]·mtbe 3. The structural parameters of the benzophenone dianion indicate that a considerable amount of its negative charge is located within the phenyl rings, rather than on the formally anionic benzylic carbon atom. The topological analysis of the electron density of the monomeric model structure [Na2(Ph2CO)] reveals an even positive charge for this particular atom, hence (Ph2CO)2− is, despite its usual representation, not a vicinal dianion." @default.
- W2148270717 created "2016-06-24" @default.
- W2148270717 creator A5019789601 @default.
- W2148270717 creator A5063987926 @default.
- W2148270717 creator A5091794897 @default.
- W2148270717 date "2006-01-01" @default.
- W2148270717 modified "2023-10-16" @default.
- W2148270717 title "Sodium compounds of the benzophenone dianion (diphenyloxidomethanide)" @default.
- W2148270717 cites W1604719872 @default.
- W2148270717 cites W173865630 @default.
- W2148270717 cites W1948866614 @default.
- W2148270717 cites W1965299221 @default.
- W2148270717 cites W1972910629 @default.
- W2148270717 cites W1976775432 @default.
- W2148270717 cites W1979492934 @default.
- W2148270717 cites W1981353016 @default.
- W2148270717 cites W1981704735 @default.
- W2148270717 cites W1983436447 @default.
- W2148270717 cites W1987853156 @default.
- W2148270717 cites W1994085779 @default.
- W2148270717 cites W1999574040 @default.
- W2148270717 cites W1999710094 @default.
- W2148270717 cites W2003839629 @default.
- W2148270717 cites W2006108771 @default.
- W2148270717 cites W2007204889 @default.
- W2148270717 cites W2010719723 @default.
- W2148270717 cites W2012667271 @default.
- W2148270717 cites W2014358987 @default.
- W2148270717 cites W2014775813 @default.
- W2148270717 cites W2018552149 @default.
- W2148270717 cites W2019287925 @default.
- W2148270717 cites W2023271753 @default.
- W2148270717 cites W2024441566 @default.
- W2148270717 cites W2027066802 @default.
- W2148270717 cites W2031147824 @default.
- W2148270717 cites W2032070236 @default.
- W2148270717 cites W2036804059 @default.
- W2148270717 cites W2043649676 @default.
- W2148270717 cites W2046015248 @default.
- W2148270717 cites W2048277924 @default.
- W2148270717 cites W2050170853 @default.
- W2148270717 cites W2050379814 @default.
- W2148270717 cites W2051469879 @default.
- W2148270717 cites W2054164390 @default.
- W2148270717 cites W2056788701 @default.
- W2148270717 cites W2057815662 @default.
- W2148270717 cites W2063603337 @default.
- W2148270717 cites W2070005238 @default.
- W2148270717 cites W2071139996 @default.
- W2148270717 cites W2075628549 @default.
- W2148270717 cites W2089622097 @default.
- W2148270717 cites W2091403016 @default.
- W2148270717 cites W2094160850 @default.
- W2148270717 cites W2094739069 @default.
- W2148270717 cites W2113557730 @default.
- W2148270717 cites W2115598712 @default.
- W2148270717 cites W2119040714 @default.
- W2148270717 cites W2122769356 @default.
- W2148270717 cites W2143981217 @default.
- W2148270717 cites W2144263794 @default.
- W2148270717 cites W2156115804 @default.
- W2148270717 cites W2157028614 @default.
- W2148270717 cites W2951017181 @default.
- W2148270717 cites W2952392850 @default.
- W2148270717 cites W2952395117 @default.
- W2148270717 cites W3005079433 @default.
- W2148270717 cites W4235261249 @default.
- W2148270717 cites W4236048302 @default.
- W2148270717 cites W4251890757 @default.
- W2148270717 cites W4293208197 @default.
- W2148270717 cites W4362225795 @default.
- W2148270717 doi "https://doi.org/10.1039/b512173f" @default.
- W2148270717 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16357968" @default.
- W2148270717 hasPublicationYear "2006" @default.
- W2148270717 type Work @default.
- W2148270717 sameAs 2148270717 @default.
- W2148270717 citedByCount "21" @default.
- W2148270717 countsByYear W21482707172012 @default.
- W2148270717 countsByYear W21482707172014 @default.
- W2148270717 countsByYear W21482707172016 @default.
- W2148270717 countsByYear W21482707172017 @default.
- W2148270717 countsByYear W21482707172018 @default.
- W2148270717 countsByYear W21482707172020 @default.
- W2148270717 countsByYear W21482707172022 @default.
- W2148270717 crossrefType "journal-article" @default.
- W2148270717 hasAuthorship W2148270717A5019789601 @default.
- W2148270717 hasAuthorship W2148270717A5063987926 @default.
- W2148270717 hasAuthorship W2148270717A5091794897 @default.
- W2148270717 hasConcept C112613896 @default.
- W2148270717 hasConcept C155647269 @default.
- W2148270717 hasConcept C166940927 @default.
- W2148270717 hasConcept C178790620 @default.
- W2148270717 hasConcept C179104552 @default.
- W2148270717 hasConcept C185592680 @default.
- W2148270717 hasConcept C2776701986 @default.
- W2148270717 hasConcept C2778279444 @default.
- W2148270717 hasConcept C2780471494 @default.
- W2148270717 hasConcept C521977710 @default.