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- W2148389634 abstract "Diallyl phthalate (DAP) was copolymerized with dialkyl fumarates, including diethyl fumarate (DEF), di-n-butyl fumarate (DBF), and di-n-octyl fumarate (DOF) by using 2,2′-azobisisobutyronitrile as an initiator at 60°C. Both rate and degree of copolymerization were quite enhanced compared with the homopolymerization of DAP and the maximum rate was found at the molar ratio of 1:1 in the monomer feed. The cyclization of DAP was almost exclusively suppressed in the Copolymerization. Gelation was promoted from 25% of the gel-point conversion for the DAP homopolymerization to 9% of the minimum one observed. Copolymerizability of DAP (M1) with dialkyl fumarates (M2) was quite high, with the following monomer reactivity ratios M2, r1, r2: DEF, 0.01, 1.25; DBF, 0.02, 1.01; DOF, 0.02, 0.96. These results are discussed in mechanistic detail." @default.
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- W2148389634 date "1982-09-01" @default.
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- W2148389634 title "Studies of the polymerization of diallyl compounds. XXXVII. Copolymerizations of diallyl phthalate with dialkyl fumarates" @default.
- W2148389634 doi "https://doi.org/10.1002/pol.1982.170200919" @default.
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