Matches in SemOpenAlex for { <https://semopenalex.org/work/W2148645087> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2148645087 endingPage "233" @default.
- W2148645087 startingPage "223" @default.
- W2148645087 abstract "The Gibbs energies of formation of $MPt_5 (Mequiv$ Nd, Dy, Ho, Er) intermetallic compounds were determined in the temperature range 900–1100 K using the solid state cell Ta,$M+MF_3|CaF_2|MPt_5+Pt+MF_3,$Ta For $M equiv$ Sm, a mixture of $Gd + GdF_3 $ was used as the reference electrode. In the case of Eu, a mixture of $Eu + EuF_2 $ served as the reference electrode. The trifluorides of Sm and Eu are not stable in equilibrium with the metal. The fluoride phase coexisting with a $SmPt_5 + Pt$ mixture is $SmF_3,$ whereas $EuF_2$ is the equilibrium phase in contact with $EuPt_5 + Pt$. All the $MPt_5$ compounds studied (except $EuPt_5)$ exhibit similar stability. Europium is divalent in the pure metal and trivalent in $EuPt_5$. The energy required for the promotion of divalent Eu to the trivalent state accounts for the less negative Gibbs energy of formation of $EuPt_5$. The enthalpies of formation of all the $MPt_5$ compounds obtained in this study are in good agreement with Miedema's model." @default.
- W2148645087 created "2016-06-24" @default.
- W2148645087 creator A5015001000 @default.
- W2148645087 creator A5063848863 @default.
- W2148645087 date "1990-08-01" @default.
- W2148645087 modified "2023-10-18" @default.
- W2148645087 title "Gibbs energies of formation of rare earth MPt5 compounds" @default.
- W2148645087 cites W1543815668 @default.
- W2148645087 cites W1987395879 @default.
- W2148645087 cites W1987873518 @default.
- W2148645087 cites W2001295307 @default.
- W2148645087 cites W2005065676 @default.
- W2148645087 cites W2026926665 @default.
- W2148645087 cites W2029969477 @default.
- W2148645087 cites W2081220424 @default.
- W2148645087 cites W2099116780 @default.
- W2148645087 cites W2135961890 @default.
- W2148645087 cites W4230547764 @default.
- W2148645087 doi "https://doi.org/10.1016/0040-6031(90)80222-k" @default.
- W2148645087 hasPublicationYear "1990" @default.
- W2148645087 type Work @default.
- W2148645087 sameAs 2148645087 @default.
- W2148645087 citedByCount "13" @default.
- W2148645087 countsByYear W21486450872014 @default.
- W2148645087 countsByYear W21486450872020 @default.
- W2148645087 countsByYear W21486450872023 @default.
- W2148645087 crossrefType "journal-article" @default.
- W2148645087 hasAuthorship W2148645087A5015001000 @default.
- W2148645087 hasAuthorship W2148645087A5063848863 @default.
- W2148645087 hasConcept C121332964 @default.
- W2148645087 hasConcept C146477669 @default.
- W2148645087 hasConcept C147789679 @default.
- W2148645087 hasConcept C185592680 @default.
- W2148645087 hasConcept C192562407 @default.
- W2148645087 hasConcept C199289684 @default.
- W2148645087 hasConcept C2983155866 @default.
- W2148645087 hasConcept C97355855 @default.
- W2148645087 hasConceptScore W2148645087C121332964 @default.
- W2148645087 hasConceptScore W2148645087C146477669 @default.
- W2148645087 hasConceptScore W2148645087C147789679 @default.
- W2148645087 hasConceptScore W2148645087C185592680 @default.
- W2148645087 hasConceptScore W2148645087C192562407 @default.
- W2148645087 hasConceptScore W2148645087C199289684 @default.
- W2148645087 hasConceptScore W2148645087C2983155866 @default.
- W2148645087 hasConceptScore W2148645087C97355855 @default.
- W2148645087 hasIssue "2" @default.
- W2148645087 hasLocation W21486450871 @default.
- W2148645087 hasOpenAccess W2148645087 @default.
- W2148645087 hasPrimaryLocation W21486450871 @default.
- W2148645087 hasRelatedWork W2063869562 @default.
- W2148645087 hasRelatedWork W2089483114 @default.
- W2148645087 hasRelatedWork W2249466452 @default.
- W2148645087 hasRelatedWork W2323190914 @default.
- W2148645087 hasRelatedWork W2351809662 @default.
- W2148645087 hasRelatedWork W2360206317 @default.
- W2148645087 hasRelatedWork W2363151802 @default.
- W2148645087 hasRelatedWork W2375469689 @default.
- W2148645087 hasRelatedWork W2386285247 @default.
- W2148645087 hasRelatedWork W2444094057 @default.
- W2148645087 hasVolume "165" @default.
- W2148645087 isParatext "false" @default.
- W2148645087 isRetracted "false" @default.
- W2148645087 magId "2148645087" @default.
- W2148645087 workType "article" @default.